Manganese,pentacarbonyl(triphenylstannyl)-, (OC-6-22)-

Base Information

Chemical Name:Manganese,pentacarbonyl(triphenylstannyl)-, (OC-6-22)-
CAS No.:14405-84-6
Molecular Formula:C23H15 Mn O5 Sn
Molecular Weight:545.017
Hs Code.:

Synonyms:Manganese,pentacarbonyl(triphenylstannyl)- (7CI,8CI); Stannane, triphenyl-, manganesecomplex; Pentacarbonyl(triphenylstannyl)manganese

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Chemical Property of Manganese,pentacarbonyl(triphenylstannyl)-, (OC-6-22)-

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of Manganese,pentacarbonyl(triphenylstannyl)-, (OC-6-22)-

There total 15 articles about Manganese,pentacarbonyl(triphenylstannyl)-, (OC-6-22)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 16972-33-1
pentacarbonylhydridomanganese

: 85317-79-9,89044-05-3
Li⁽¹⁺⁾*Mn₂(CO)9(CHO)^(1-)=Li(Mn₂(CO)9(CHO))

: 639-58-7
triphenyltin chloride

: 10170-69-1
dimanganese decacarbonyl

: 14405-84-6
triphenyltinmanganesepentacarbonyl

: 1333-74-0
hydrogen

Guidance literature:: In tetrahydrofuran; under N2, soln. of HMn(CO)5 in THF was cooled to -23°C, added tosoln. of formyl-complex in THF (-23°C), warmed slowly to room temp., Ph3SnCl was added, stirred for 1 h; solvent removed by rotary evapn., vac. sublimed at 60°C, residueeluted through silica gel column with ethyl acetate-hexane;

Reference yield: 95.0%

: 14516-54-2
bromopentacarbonylmanganese(I)

: 639-58-7
triphenyltin chloride

: 14405-84-6
triphenyltinmanganesepentacarbonyl

Guidance literature:: With sodium tetrahydroborate; In dichloromethane; water; soln. of starting Mn complex was added to the soln. of NaBH4 and BTEAC at room temp. during 7 h with stirring, aq. layer was siphoned out and org. layer was washed with water, dried over MgSO4, addn. of tin compd., stirring for 0.5 h; filtration, removal of solvent under vac., extn. of residue with hot hexane followed by crystn.;
DOI:10.1016/S0022-328X(00)81005-0

Reference yield: 93.0%

: 74343-84-3
N(CH₃)4⁽¹⁺⁾*Mn(CO)5^(1-) = N(CH₃)4Mn(CO)5

: 639-58-7
triphenyltin chloride

: 14405-84-6
triphenyltinmanganesepentacarbonyl

Guidance literature:: In acetone; under N2, Mn-compd. dissolved, soln. of (C6H5)3SnCl added, stirred at room temp. for 30 min; water added, filtrated, dried in vacuo;
DOI:10.1021/ja00528a034