BrTi(OiPr)3

Base Information

• Chemical Name: BrTi(OiPr)3
• CAS No.: 57833-68-8
• Molecular Formula: C₉H₂₁BrO₃Ti
• Molecular Weight: 305.048
• Mol file: 57833-68-8.mol

Synonyms:BrTi(OiPr)3

Chemical Property of BrTi(OiPr)3

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of BrTi(OiPr)3

There total 15 articles about BrTi(OiPr)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyltitanium triisopropoxide (73085-90-2) + allyl bromide (106-95-6) → BrTi(OiPr)3 (57833-68-8) + 4-Phenylbut-1-ene (768-56-9)

Guidance literature:

bis(η3-allyl-μ-chloropalladium(II)); In tetrahydrofuran; reaction of soln. of PhCH2Ti(i-OPr)3 (obtained from reaction of PhCH2MgBr with ClTi(i-OPr)3) with soln. of bromide and (C3H5PdCl)2 in THF at 20°C under Ar;; not isolated;;

DOI:10.1007/BF00959380

Reference yield:

4-methoxyphenyltitanium triisopropoxide (103594-89-4) + allyl bromide (106-95-6) → Estragole (140-67-0) + BrTi(OiPr)3 (57833-68-8)

Guidance literature:

bis(η3-allyl-μ-chloropalladium(II)); In diethyl ether; benzene; reaction of soln. of p-MeOC6H4Ti(i-OPr)3 in ether (obtained from reaction of p-MeOC6H4MgBr with ClTi(i-OPr)3 in ether) with soln. of bromide and (C3H5PdCl)2 in benzene at 20°C under Ar;; not isolated;;

DOI:10.1007/BF00959380

Reference yield:

(E/Z)-crotyl bromide (4784-77-4,29576-14-5,39616-19-8) + phenyltriisopropoxytitanium(IV) (16635-23-7) → BrTi(OiPr)3 (57833-68-8) + 1-phenyl-2-butene (1560-06-1)

Guidance literature:

bis(η3-allyl-μ-chloropalladium(II)); In diethyl ether; benzene; reaction of soln. of PhTi(i-OPr)3 in ether (obtained from reaction of PhLi with ClTi(i-OPr)3 in ether) with soln. of bromide and (C3H5PdCl)2 in benzene at 20°C under Ar;; not isolated;;

DOI:10.1007/BF00959380

upstream raw materials:

(E/Z)-crotyl bromide

phenyltriisopropoxytitanium(IV)

methyltriisopropoxytitanium(IV)

Cinnamyl bromide