phenyltriisopropoxytitanium(IV)

Base Information

• Chemical Name: phenyltriisopropoxytitanium(IV)
• CAS No.: 16635-23-7
• Molecular Formula: C₁₅H₂₆O₃Ti
• Molecular Weight: 302.25
• Mol file: 16635-23-7.mol

Synonyms:phenyltriisopropoxytitanium(IV)

Chemical Property of phenyltriisopropoxytitanium(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyltriisopropoxytitanium(IV)

There total 7 articles about phenyltriisopropoxytitanium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

triisopropoxytitanium(IV) chloride (20717-86-6) + phenylmagnesium bromide (100-58-3) → phenyltriisopropoxytitanium(IV) (16635-23-7)

Guidance literature:

In tetrahydrofuran; at -15 - 20 ℃; for 0.5h; Glovebox;

DOI:10.1021/jacs.9b05671

Reference yield:

titanium(IV) isopropylate (546-68-9) + phenylmagnesium chloride (100-59-4) → phenyltriisopropoxytitanium(IV) (16635-23-7)

Guidance literature:

With titanium tetrachloride; In tetrahydrofuran; at -20 - 20 ℃; for 3.5h; Inert atmosphere;

DOI:10.1007/s00706-021-02796-6

Reference yield:

triisopropoxytitanium(IV) chloride (20717-86-6) + phenyllithium (591-51-5) → phenyltriisopropoxytitanium(IV) (16635-23-7)

Guidance literature:

In tetrahydrofuran; under N2; addn. of C6H5Li to a soln. of ClTi(OCHMe2)3 in THF;; not isolated;;

upstream raw materials:

triisopropoxytitanium(IV) chloride

phenyllithium

bromobenzene

titanium(IV) isopropylate

Downstream raw materials:

biphenyl

3-phenylbut-1-ene

1-phenyl-2-butene

1-phenylpropadiene