aminodiborane

Base Information

• Chemical Name: aminodiborane
• CAS No.: 39046-41-8
• Molecular Formula: B₂H₇N
• Molecular Weight: 42.6843
• Mol file: 39046-41-8.mol

Synonyms:aminodiborane

Chemical Property of aminodiborane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of aminodiborane

There total 9 articles about aminodiborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

borane-ammonia complex (10043-11-5) → aminodiborane (39046-41-8) + borazine (6569-51-3) + hydrogen (1333-74-0) + borohydride

Guidance literature:

With 1,8-bis(dimethylamino)naphthalene; In further solvent(s); under N2 or He; mixt. of ammonia borane and proton sponge in tetraglyme heated at 85°C; H2 gas release measurement, evacuation through cold trap, extn. with glyme, NMR detection; Kinetics;

DOI:10.1021/ja905015x

Reference yield:

borane-ammonia complex (10043-11-5) + trifluorormethanesulfonic acid (1493-13-6) → BH2(NH3)2(1+) + aminodiborane (39046-41-8) + hydrogen (1333-74-0)

Guidance literature:

In 1,2-dimethoxyethane; in Schlenk flask; solid H3NBH3 added to soln. of trifluoromethanesulfonic acid (25 mol.-%) in glyme; heated at 60°C for 18 h;

DOI:10.1002/anie.200603285

Reference yield:

borane-ammonia complex (10043-11-5) + tris(pentafluorophenyl)borate (1109-15-5) → aminodiborane (39046-41-8) + BH2(NH3)2(1+)*HB(C6F5)3(1-)=[BH2(NH3)2][HB(C6F5)3] + hydrogen (1333-74-0)

Guidance literature:

In further solvent(s); in Schlenk flask; solid H3NBH3 added to soln. of B(C6F5)3 (0.5 mol.-%) in tetraglyme; heated at 60°C for 20 h;

DOI:10.1002/anie.200603285

upstream raw materials:

diborane

borane-ammonia complex

trifluorormethanesulfonic acid

tris(pentafluorophenyl)borate

Downstream raw materials:

metaboric acid

ammonia borane

diborane

(1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-methylidene)H₂BNH₂-BH₃