{Ir2(H)2(CO)2(μ-Cl)(bis(diphenylphosphino)methane)2}{BF4}

Base Information

Chemical Name:{Ir2(H)2(CO)2(μ-Cl)(bis(diphenylphosphino)methane)2}{BF4}
CAS No.:97690-07-8
Molecular Formula:BF₄*C₅₂H₄₆ClIr₂O₂P₄
Molecular Weight:1333.53
Hs Code.:

Synonyms:{Ir2(H)2(CO)2(μ-Cl)(bis(diphenylphosphino)methane)2}{BF4}

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Chemical Property of {Ir2(H)2(CO)2(μ-Cl)(bis(diphenylphosphino)methane)2}{BF4}

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Technology Process of {Ir2(H)2(CO)2(μ-Cl)(bis(diphenylphosphino)methane)2}{BF4}

There total 2 articles about {Ir2(H)2(CO)2(μ-Cl)(bis(diphenylphosphino)methane)2}{BF4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 90552-98-0
Ir₂Cl(CO)2(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*BF₄^(1-)=Ir₂Cl(CO)2(((C₆H₅)2P)2CH₂)2BF₄

: 97690-07-8
{Ir2(H)2(CO)2(μ-Cl)(bis(diphenylphosphino)methane)2}{BF4}

Guidance literature:: With H₂; In tetrahydrofuran; stirring as a slurry in THF under 1 atm of H2 for 15 min, solid diappearing to give a clear light yellow soln., H2 replacing to N2, refluxing for 20 min, taking to dryness under a stream of N2; purified by recrystallization from CH2Cl2-Et2O, identified by elem. anal., IR and NMR spectra;

Reference yield: 85.0%

: 14104-20-2
silver tetrafluoroborate

: 97690-03-4
Ir₂H₂Cl₂(CO)2(((C₆H₅)2P)2CH₂)2

: 97690-07-8
{Ir2(H)2(CO)2(μ-Cl)(bis(diphenylphosphino)methane)2}{BF4}

Guidance literature:: In tetrahydrofuran; 1 equiv of AgBF4 adding to a slurry of the complex in THF under N2, color changing to bright yellow and a yellow ppt. appe? taking to dryness under a stream of N2, extd. with CH2Cl2, filtering under N2, Et2O adding, ppt. sepg.; identified by elem. anal., IR and NMR spectra;

Reference yield: 50.0%

: 97690-07-8
{Ir2(H)2(CO)2(μ-Cl)(bis(diphenylphosphino)methane)2}{BF4}

: 97690-09-0
Ir₂(CH₃OCOCCHCOOCH₃)2Cl₂(CO)2(((C₆H₅)2P)2CH₂)2

Guidance literature:: With DMA; In dichloromethane; an excess of the ligand adding to a soln. of the complex under N2, color changing from yellow to orange, stirring for 12 h, Et2O adding, ppt. sepg.; purified by column chromy. on Florisil, identified by elem. anal., IR, NMR spectra and single crystal X-ray diffraction;