2-Formyl-6-methylcyclohexanone sodium salt

Base Information

Chemical Name:2-Formyl-6-methylcyclohexanone sodium salt
CAS No.:86096-08-4
Molecular Formula:C₈H₁₁O₂*Na
Molecular Weight:162.164
Hs Code.:

Synonyms:2-Formyl-6-methylcyclohexanone sodium salt

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Chemical Property of 2-Formyl-6-methylcyclohexanone sodium salt

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Technology Process of 2-Formyl-6-methylcyclohexanone sodium salt

There total 1 articles about 2-Formyl-6-methylcyclohexanone sodium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 583-60-8
2-Methylcyclohexanone

: 109-94-4
formic acid ethyl ester

: 86096-08-4
2-Formyl-6-methylcyclohexanone sodium salt

Guidance literature:: With sodium methylate; In diethyl ether; for 18h; Ambient temperature;
DOI:10.1021/jo00348a043

Reference yield:

: 86096-08-4
2-Formyl-6-methylcyclohexanone sodium salt

: 63531-93-1
18-Hydroxyretinoic acid

Guidance literature:: Multi-step reaction with 10 steps

1: 1.) potassium amide / 1.) liq. NH₃, reflux, 1 h, 2.) liq. NH₃, ether, 3 h

2: 90 percent / potassium carbonate / acetone / 6 h / Heating

3: 1.) n-butyllithium / 1.) THF, hexane, -65 - 0 deg C, 2.) -65 deg C up to room temp., 1 h

4: 1 N H₂SO₄ / acetone / 0.5 h

5: LiAlH₄ / diethyl ether / 3 h / Ambient temperature

6: pyridine / diethyl ether / 2 h / Ambient temperature

7: 99 percent / CH₂Cl₂ / 1 h / Ambient temperature

8: sodium methoxide / CH₂Cl₂; methanol / 0.17 h / 0 - 5 °C

9: triethylamine / bis(benzonitrile)palladium dichloride / acetonitrile / 1 h / Ambient temperature

10: potassium hydroxide / methanol; H₂O / 0.5 h / Heating

With pyridine; potassium hydroxide; lithium aluminium tetrahydride; n-butyllithium; sulfuric acid; sodium methylate; potassium carbonate; potassium amide; triethylamine; bis(benzonitrile)palladium(II) dichloride; In methanol; diethyl ether; dichloromethane; water; acetone; acetonitrile;
DOI:10.1021/jo00348a043

Reference yield:

: 86096-08-4
2-Formyl-6-methylcyclohexanone sodium salt

: 81121-51-9
(2E,4E,6E,8E)-9-[2-(1-Ethoxy-ethoxymethyl)-6,6-dimethyl-cyclohex-1-enyl]-3,7-dimethyl-nona-2,4,6,8-tetraenoic acid

Guidance literature:: Multi-step reaction with 12 steps

1: 1.) potassium amide / 1.) liq. NH₃, reflux, 1 h, 2.) liq. NH₃, ether, 3 h

2: 90 percent / potassium carbonate / acetone / 6 h / Heating

3: 1.) n-butyllithium / 1.) THF, hexane, -65 - 0 deg C, 2.) -65 deg C up to room temp., 1 h

4: 1 N H₂SO₄ / acetone / 0.5 h

5: LiAlH₄ / diethyl ether / 3 h / Ambient temperature

6: pyridine / diethyl ether / 2 h / Ambient temperature

7: 99 percent / CH₂Cl₂ / 1 h / Ambient temperature

8: sodium methoxide / CH₂Cl₂; methanol / 0.17 h / 0 - 5 °C

9: triethylamine / bis(benzonitrile)palladium dichloride / acetonitrile / 1 h / Ambient temperature

10: 13.4 g / potassium hydroxide / methanol; H₂O / 0.17 h / Ambient temperature

11: p-toluenesulfonic acid / diethyl ether / 0.17 h / Ambient temperature

12: potassium hydroxide / methanol; H₂O / 0.17 h / Heating

With pyridine; potassium hydroxide; lithium aluminium tetrahydride; n-butyllithium; sulfuric acid; sodium methylate; potassium carbonate; toluene-4-sulfonic acid; potassium amide; triethylamine; bis(benzonitrile)palladium(II) dichloride; In methanol; diethyl ether; dichloromethane; water; acetone; acetonitrile;
DOI:10.1021/jo00348a043