(1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane-P)gold(I) bromide chloride

Base Information

• Chemical Name: (1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane-P)gold(I) bromide chloride
• CAS No.: 1234455-39-0
• Molecular Formula: Br*C₁₃H₁₉AuClN₃P
• Molecular Weight: 560.611
• Mol file: 1234455-39-0.mol

Synonyms:(1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane-P)gold(I) bromide chloride

Chemical Property of (1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane-P)gold(I) bromide chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane-P)gold(I) bromide chloride

There total 1 articles about (1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane-P)gold(I) bromide chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + 1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane bromide (1234455-26-5) → (1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane-P)gold(I) bromide chloride (1234455-39-0)

Guidance literature:

In acetone; ligand added to mixt. of AuCl(C4H8S) in acetone at room temp., stirred for 14 h at room temp.; Et2O added, filtered, washed with Et2O, dried in vacuo; elem. anal.;

DOI:10.1016/j.poly.2010.03.012

Reference yield: 86.0%

(1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane-P)gold(I) bromide chloride (1234455-39-0) + 2-sulfanylpyrimidine (131242-36-9) → [Au(Spyrim)(1,3,5-triaza-7-phosphaadamantane-CH2Ph)]Br (1609567-54-5)

Guidance literature:

With potassium hydroxide; In methanol; at 20 ℃; for 12h;

DOI:10.1016/j.ejmech.2014.04.001

Reference yield: 78.0%

(1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane-P)gold(I) bromide chloride (1234455-39-0) → [AuBr(1,3,5-triaza-7-phosphaadamantane-CH2Ph)]Br (1431464-08-2)

Guidance literature:

With sodium bromide; In acetone; for 24h;

DOI:10.1002/ejic.201201411

upstream raw materials:

(tetrahydrothiophene)gold(I) chloride

1-benzyl-3,5-diaza-1-azonia-7-phosphatricyclo[3.3.1.1(3,7)]decane bromide

Downstream raw materials:

[AuBr(1,3,5-triaza-7-phosphaadamantane-CH₂Ph)]Br

[Au(Spy)(1,3,5-triaza-7-phosphaadamantane-CH₂Ph)]Br

[Au(Spyrim)(1,3,5-triaza-7-phosphaadamantane-CH₂Ph)]Br

[Au(SMepyrim)(1,3,5-triaza-7-phosphaadamantane-CH₂Ph)]Br