triphenyl<1-methyl-2-((phenyl(methoxycarbonyl)methylene)hydrazono)propyl>phosphonium iodide

Base Information

• Chemical Name: triphenyl<1-methyl-2-((phenyl(methoxycarbonyl)methylene)hydrazono)propyl>phosphonium iodide
• CAS No.: 107769-76-6
• Molecular Formula: C₃₁H₃₀N₂O₂P*I
• Molecular Weight: 620.47
• Mol file: 107769-76-6.mol

Synonyms:triphenyl<1-methyl-2-((phenyl(methoxycarbonyl)methylene)hydrazono)propyl>phosphonium iodide

Chemical Property of triphenyl<1-methyl-2-((phenyl(methoxycarbonyl)methylene)hydrazono)propyl>phosphonium iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triphenyl<1-methyl-2-((phenyl(methoxycarbonyl)methylene)hydrazono)propyl>phosphonium iodide

There total 4 articles about triphenyl<1-methyl-2-((phenyl(methoxycarbonyl)methylene)hydrazono)propyl>phosphonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

triphenyl<2-((phenyl(methoxycarbonyl)methylene)hydrazono)propylidene>phosphorane (107769-74-4) + methyl iodide (74-88-4) → triphenyl<1-methyl-2-((phenyl(methoxycarbonyl)methylene)hydrazono)propyl>phosphonium iodide (107769-76-6)

Guidance literature:

In acetonitrile; for 0.5h; Heating;

DOI:10.1021/jo00385a029

Reference yield:

methyl 2-oxo-2-phenylacetate (15206-55-0) → triphenyl<1-methyl-2-((phenyl(methoxycarbonyl)methylene)hydrazono)propyl>phosphonium iodide (107769-76-6)

Guidance literature:

Multi-step reaction with 4 steps

1: 53 percent / aq. hydrazine, aq. HCl / methanol / 96 h / Ambient temperature

2: 75 percent / CH₂Cl₂ / 4 h / Heating

3: 85 percent / KOH / methanol / 0.5 h / -5 °C

4: 83 percent / acetonitrile / 0.5 h / Heating

With hydrogenchloride; potassium hydroxide; hydrazine hydrate; In methanol; dichloromethane; acetonitrile;

DOI:10.1021/jo00385a029

Reference yield:

methyl α-hydrazonophenylacetate (23102-11-6) → triphenyl<1-methyl-2-((phenyl(methoxycarbonyl)methylene)hydrazono)propyl>phosphonium iodide (107769-76-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 75 percent / CH₂Cl₂ / 4 h / Heating

2: 85 percent / KOH / methanol / 0.5 h / -5 °C

3: 83 percent / acetonitrile / 0.5 h / Heating

With potassium hydroxide; In methanol; dichloromethane; acetonitrile;

DOI:10.1021/jo00385a029

upstream raw materials:

triphenyl<2-((phenyl(methoxycarbonyl)methylene)hydrazono)propylidene>phosphorane

methyl iodide

methyl 2-oxo-2-phenylacetate

methyl α-hydrazonophenylacetate

Downstream raw materials:

trans-5,10-bis(methoxycarbonyl)-5,10-diphenylpyrazolo<1,5-a:1',5'-e><1,5>diaza<3,6>dithiocine

{[2-[4-(2-{[1-Methoxycarbonyl-1-phenyl-meth-(Z)-ylidene]-hydrazono}-1-methyl-propylidene)-[1,3]dithietan-2-ylidene]-1-methyl-prop-(Z)-ylidene]-hydrazono}-phenyl-acetic acid methyl ester

6,7-dimethyl-3-methoxy-3-phenyl-1-(2,6-dimethylphenyl)-1H-imidazo<1,2-b>pyrazol-2(3H)-one

triphenyl<1-methyl-2-((phenyl(methoxycarbonyl)methylene)hydrazono)propylidene>phosphorane