Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98%

Base Information

• Chemical Name: Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98%
• CAS No.: 863971-63-5
• Molecular Formula: C20H35 N2 O P Ru
• Molecular Weight: 451.554
• Mol file: 863971-63-5.mol

Synonyms:Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98%

Chemical Property of Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98%

Chemical Property:

• PSA: 21.76000
• LogP: 4.64480
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: air sensitive, store cold

Purity/Quality:

97% ^*data from raw suppliers

Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Milstein Catalyst ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98%

There total 6 articles about Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

C21H37N2O3PRu → carbonylhydrido[6-(di-tert-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II) (863971-63-5) + potassium formate (590-29-4)

Guidance literature:

With potassium tert-butylate; at 25 ℃; for 0.0833333h;

DOI:10.1021/cs400609u

Reference yield:

C27H41N2O2PRu (1448532-82-8,1448816-50-9) → carbonylhydrido[6-(di-tert-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II) (863971-63-5) + benzaldehyde (100-52-7)

Guidance literature:

In benzene-d6; at 25 ℃; for 0.5h; Inert atmosphere; Glovebox;

DOI:10.1039/c3cc43517b

Reference yield:

[(2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine]Ru(hydride)2(carbonyl) (863971-64-6) → carbonylhydrido[6-(di-tert-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II) (863971-63-5) + hydrogen (1333-74-0)

Guidance literature:

In solid; Ru complex was kept at room temp.;

DOI:10.1021/ja052862b

upstream raw materials:

[(2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine]Ru(hydride)2(carbonyl)

C₂₇H₄₁N₂O₂PRu

C₂₅H₄₃N₂O₂PRu