tris(2-fluorophenyl)borane

Base Information

Chemical Name:tris(2-fluorophenyl)borane
CAS No.:146355-10-4
Molecular Formula:C₁₈H₁₂BF₃
Molecular Weight:296.099
Hs Code.:

Synonyms:tris(2-fluorophenyl)borane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tris(2-fluorophenyl)borane

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Technology Process of tris(2-fluorophenyl)borane

There total 1 articles about tris(2-fluorophenyl)borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

: 348-52-7
1-Fluoro-2-iodobenzene

: 353-42-4
boron trifluoride dimethyl etherate

: 146355-10-4
tris(2-fluorophenyl)borane

Guidance literature:: With magnesium; In diethyl ether; react. of 41mmol 2-FC6H4I in 25ml ether with 41mmol Mg in 10ml ether at -20°C; dropwise addn. of 13mmol BF3*OMe2 in 40ml ether at -20°C; warming to room temp.;; removal of Mg-salts by filtration; crystn. from the filtrate; recrystn. from n-hexane; detn. by (13)C-, (19)F-, (1)H-NMR, mass spectroscopy;;

Reference yield: 70.0%

: 250724-55-1
C₆H₃F₄I

: 146355-10-4
tris(2-fluorophenyl)borane

: C₁₂H₇F₃I⁽¹⁺⁾*BF₄^(1-)

Guidance literature:: With boron trifluoride dimethyl etherate; In dichloromethane; at -40 ℃; for 25h;
DOI:10.1016/S0022-1139(99)00118-9

Reference yield: 7.0%

: 13709-36-9
xenon difluoride

: 109-63-7
trifluoroborane diethyl ether

: 146355-10-4
tris(2-fluorophenyl)borane

: 147069-75-8
{Xe(2-FC₆H₄)}{BF₄}

Guidance literature:: In dichloromethane; byproducts: Et2O; dropwise addn. of XeF2 in CH2Cl2 (-40.deggree.C) to CH2Cl2 soln. of arylborane and BF3*Et2O (-40°C, stirring); pptn. on standing (ice temp., 2 days), filtration of (-78°C), washing (cold CH2Cl2), drying (vac.);