bis(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato^(2-)]-iron(II)

Base Information

• Chemical Name: bis(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato^(2-)]-iron(II)
• CAS No.: 75557-96-9
• Molecular Formula: C₇₂H₇₆FeN₁₂O₄
• Molecular Weight: 1229.32

Synonyms:bis(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato^(2-)]-iron(II)

Chemical Property of bis(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato^(2-)]-iron(II)

Chemical Property:

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Technology Process of bis(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato^(2-)]-iron(II)

There total 3 articles about bis(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato^(2-)]-iron(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

1-methyl-1H-imidazole (616-47-7) + bromo{(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)-phenyl]porphyrinato(2-)}-iron(III) → bis(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato(2-)]-iron(II) (75557-96-9)

Guidance literature:

With chromium(II) diacetylacetonate; In tetrahydrofuran; for 0.0833333h; Inert atmosphere; Schlenk technique; Glovebox; Heating;

DOI:10.1039/c5dt04563k

Reference yield:

1-methyl-1H-imidazole (616-47-7) + chloroiron(III) meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate (105118-92-1,92078-42-7,87334-91-6,86107-94-0,87334-93-8,87334-92-7,104486-25-1) → {Fe(meso-5,10,15,20-tetrakis(o-pivalamidophenyl)porphyrinato)(1-methylimidazole)2} (52275-89-5,75557-96-9)

Guidance literature:

With sodium dithionite; In water; benzene; a benzene soln. of the porphyrin and a ligand adding to H2O, after carefully removal of O2 the flask filling with Ar, solid Na2S2O4 adding, stirring for 30 min (UV monitoring), treating with anhydrous Na2SO4, solidsfiltering off, hexane adding; identified by UV spectrum;

DOI:10.1021/ja00301a016

Reference yield:

1-methyl-1H-imidazole (616-47-7) + [(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato(2-)]-iron(II) (52629-13-7,83198-46-3,126783-80-0) → bis(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato(2-)]-iron(II) (75557-96-9)

Guidance literature:

In ⁽²⁾H₈-toluene; Fe-complex was reacted with an excess of N-methylimidazole in toluene-d8 soln.; detected by NMR (1)H;

DOI:10.1021/ja00386a027

upstream raw materials:

1-methyl-1H-imidazole

chloroiron(III) meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate

[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato^(2-)]-iron(II)

Downstream raw materials:

chloroiron(III) meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate

(5,10,15,20-tetrakis(α,α,α,α-O-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(O2)

(O2)iron(1-methylimidazole)(α,α,α,α-5,10,15,20-tetrakis[o-pivalamidophenyl]porphyrinate)

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