(15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)(tert-butyl)dimethylsilane

Base Information

Chemical Name:(15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)(tert-butyl)dimethylsilane
CAS No.:1112844-78-6
Molecular Formula:C₄₆H₇₆O₅Si
Molecular Weight:737.192
Hs Code.:

Synonyms:(15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)(tert-butyl)dimethylsilane

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Chemical Property of (15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)(tert-butyl)dimethylsilane

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Technology Process of (15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)(tert-butyl)dimethylsilane

There total 1 articles about (15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1112844-76-4
(1R,2R,5S,7R)-7-(5-(benzyloxy)pentyl)-5-(15-(tert-butyldimethylsilyloxy)pentadecyl)-6,8-dioxabicyclo[3.2.1]octan-2-ol

: 100-39-0
benzyl bromide

: 1112844-78-6
(15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)(tert-butyl)dimethylsilane

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 0 ℃; for 1h;
DOI:10.1016/j.tetlet.2008.10.137

Reference yield: 88.0%

: 1112844-78-6
(15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)(tert-butyl)dimethylsilane

: 1112844-80-0
15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxa-bicyclo[3.2.1]octan-5-yl)pentadecan-1-ol

Guidance literature:: With toluene-4-sulfonic acid; In methanol; at 20 ℃; for 1h;
DOI:10.1016/j.tetlet.2008.10.137

Reference yield:

: 1112844-78-6
(15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)(tert-butyl)dimethylsilane

: 1112844-45-7
C₄₁H₆₄O₇S

Guidance literature:: Multi-step reaction with 2 steps

1.1: toluene-4-sulfonic acid / methanol / 0.5 h / 20 °C

2.1: triethylamine / dichloromethane / 0.5 h / 0 °C

2.2: 0.5 h / 0 °C

With toluene-4-sulfonic acid; triethylamine; In methanol; dichloromethane;
DOI:10.1016/j.tet.2012.12.045