Pt(H)(NCCH₃)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(H)(NCCH₃)P₂(C₆H₅)6]BF₄

Base Information

Chemical Name:Pt(H)(NCCH₃)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(H)(NCCH₃)P₂(C₆H₅)6]BF₄
CAS No.:76706-33-7
Molecular Formula:BF₄*C₃₈H₃₄NP₂Pt
Molecular Weight:848.527
Hs Code.:

Pt(H)(NCCH<sub>3</sub>)[P(C<sub>6</sub>H<sub>5</sub>)3]2<sup>(1+)</sup>*BF<sub>4</sub><sup>(1-)</sup>=[Pt(H)(NCCH<sub>3</sub>)P<sub>2</sub>(C<sub>6</sub>H<sub>5</sub>)6]BF<sub>4</sub>

Synonyms:Pt(H)(NCCH₃)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(H)(NCCH₃)P₂(C₆H₅)6]BF₄

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Chemical Property of Pt(H)(NCCH₃)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(H)(NCCH₃)P₂(C₆H₅)6]BF₄

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Technology Process of Pt(H)(NCCH₃)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(H)(NCCH₃)P₂(C₆H₅)6]BF₄

There total 2 articles about Pt(H)(NCCH₃)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(H)(NCCH₃)P₂(C₆H₅)6]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 14104-20-2
silver tetrafluoroborate

: 21005-75-4,16970-27-7
trans-(triphenylphosphane)2PtHBr

: 75-05-8,26809-02-9
acetonitrile

: 76706-33-7
Pt(H)(NCCH₃)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(H)(NCCH₃)P₂(C₆H₅)6]BF₄

Guidance literature:: With charcoal; In dichloromethane; acetone; Treating of Pt-compd. in CH2Cl2 with acetone soln. of AgBF4 and then with excess of CH3CN under N2. Stirring of react. mixt. at room temp. for 1 h and for addnl. 15 min with activated charcoal.; Filtn., evapn. of filtrate under reduced pressure and then treatment with Et2O. Filtn. of ppt., washing (Et2O), vac.-drying, elem. anal.;

Reference yield:

: 14104-20-2
silver tetrafluoroborate

: 16841-99-9,25879-12-3,16902-93-5
trans-chlorohydridobis(triphenylphosphine)platinum(II)

: 75-05-8,26809-02-9
acetonitrile

: 76706-33-7
Pt(H)(NCCH₃)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(H)(NCCH₃)P₂(C₆H₅)6]BF₄

Guidance literature:: In acetonitrile; byproducts: AgCl; a soln. of Pt-complex in CH3CN was treated with a soln. of AgBF4 in CH3CN, stirred for 5 min at room temp.; filtered, washed with CH2Cl2, evapd.;
DOI:10.1016/S0022-328X(00)81388-1

Reference yield: 45.0%

: 76706-33-7
Pt(H)(NCCH₃)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(H)(NCCH₃)P₂(C₆H₅)6]BF₄

: 107-07-3
2-chloro-ethanol

: 16841-99-9,25879-12-3,16902-93-5
trans-chlorohydridobis(triphenylphosphine)platinum(II)

: 154648-55-2
PtH[NC(CH₃)OCH₂CH₂][P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[PtH[NC(CH₃)OCH₂CH₂]P₂(C₆H₅)6]BF₄

Guidance literature:: With n-C₄H₉Li; In tetrahydrofuran; hexane; Treating soln. of ClC2H4OH in THF (-8°C) with n-BuLi (n-hexane) followed by Pt-compd. leads to formation of clear soln. after 1 min. Mixt. is allowed to reach room temp. (10 min).; Concn., addn. of Et2O, filtn., drying of soln., taking up with Et2O. IRand GLC/MS spectra show presence of free oxazoline. Sepn. of Pt-compds.by taking advantage of the higher solubility of chloro-complex in benzene. Elem. anal. of Pt-oxazoline compd.;