2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1-selena-2-germacyclohex-4-ene

Base Information

• Chemical Name: 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1-selena-2-germacyclohex-4-ene
• CAS No.: 163273-58-3
• Molecular Formula: C₄₈H₉₂GeSeSi₆
• Molecular Weight: 989.321
• Mol file: 163273-58-3.mol

Synonyms:2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1-selena-2-germacyclohex-4-ene

Chemical Property of 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1-selena-2-germacyclohex-4-ene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1-selena-2-germacyclohex-4-ene

There total 6 articles about 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1-selena-2-germacyclohex-4-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-5-(2,4,6-triisopropylphenyl)-1,2,3,4,5-tetraselenagermolane (142573-06-6) + 2,3-dimethyl-buta-1,3-diene (513-81-5) + triphenylphosphine (603-35-0) → 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1-selena-2-germacyclohex-4-ene (163273-58-3)

Guidance literature:

In hexane; 90°C, 2h; room temp. , 10 h;

DOI:10.1021/ja991147x

Reference yield: 84.0%

[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](2,4,6-triisopropylphenyl)germaneselone (163273-57-2) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1-selena-2-germacyclohex-4-ene (163273-58-3)

Guidance literature:

In hexane; heating of the components in hexane in a closed ampoule to 100°C;

Reference yield:

(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)dibromo(2,4,6-triisopropylphenyl)germane (162088-75-7) → 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1-selena-2-germacyclohex-4-ene (163273-58-3)

Guidance literature:

Multi-step reaction with 3 steps

1: LiC₁₀H₈ / tetrahydrofuran

2: tetrahydrofuran

3: hexane

With LiC₁₀H₈; In tetrahydrofuran; hexane;

DOI:10.1021/ja991147x

upstream raw materials:

[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](2,4,6-triisopropylphenyl)germaneselone

2,3-dimethyl-buta-1,3-diene

5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-5-(2,4,6-triisopropylphenyl)-1,2,3,4,5-tetraselenagermolane

triphenylphosphine

Downstream raw materials:

2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4-mesityl-1,3,5,2-oxaselenazagermole