{4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium

Base Information

Chemical Name:{4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium
CAS No.:108295-88-1
Molecular Formula:C₁₈H₁₆CrO₃
Molecular Weight:337.28
Hs Code.:

Synonyms:{4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium

Suppliers and Price of {4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium

There total 2 articles about {4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 2206-27-1
dimethylsulfoxide-d6

: 108319-38-6
tricarbonyl(4,4'-dimethyldiphenylmethane)chromium

: 108295-88-1
{4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium

Guidance literature:: With sodium hydride; In dimethylsulfoxide-d6; byproducts: HD; addn. of Me2SO-d6 to NaH; heating, 70°C, 1h; cooling to room temp; addn. of Cr complex soln.; stirring, 10h; quenching with D2O; neutralization with satd. ammonium chloride; extn. (ether); addn. of silica gel; evapn.; chromy. (silica, hexane/ethyl acetate); recrystn. (hexane);
DOI:10.1021/ja00247a022

Reference yield:

: 108295-88-1
{4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium

: 1076-43-3
benzene-d6

: 38095-88-4
(benzene-d6)tricarbonylchromium

: 4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane

: 108295-88-1
{4'-(trideuteriomethyl)-4-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium

Guidance literature:: With catalyst: acetone-d6; In [⁽²⁾H₆]acetone; benzene-d6; Cr-complex was heated in benzene-d6 in the presence of acetone-d6 (0.2 - 1.0 M) at 170°C; rate consts. are given; (1)H NMR analysis of reaction mixt.; Kinetics;

Reference yield:

: 108295-88-1
{4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium

: 697302-50-4,697302-51-5,12082-08-5,697302-53-7
(benzene)tricarbonylchromium

Guidance literature:: With benzene; In benzene; byproducts: CD3C6H4CD2C6H4CH3; at 170°C; monitoring by 1H NMR; Kinetics;
DOI:10.1021/ja00247a022