(benzene-d6)tricarbonylchromium

Base Information

• Chemical Name: (benzene-d6)tricarbonylchromium
• CAS No.: 38095-88-4
• Molecular Formula: C₉H₆CrO₃
• Molecular Weight: 220.093
• Mol file: 38095-88-4.mol

Synonyms:

Chemical Property of (benzene-d6)tricarbonylchromium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (benzene-d6)tricarbonylchromium

There total 6 articles about (benzene-d6)tricarbonylchromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium (108295-88-1) + benzene-d6 (1076-43-3) → (benzene-d6)tricarbonylchromium (38095-88-4) + 4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane + {4'-(trideuteriomethyl)-4-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium (108295-88-1)

Guidance literature:

With catalyst: acetone-d6; In [⁽²⁾H₆]acetone; benzene-d6; Cr-complex was heated in benzene-d6 in the presence of acetone-d6 (0.2 - 1.0 M) at 170°C; rate consts. are given; (1)H NMR analysis of reaction mixt.; Kinetics;

Reference yield:

(1,4-diphenylbutane)bis(tricarbonylchromium) (108319-37-5) + benzene-d6 (1076-43-3) → (benzene-d6)tricarbonylchromium (38095-88-4) + (1,4-diphenylbutane)tricarbonylchromium (36153-04-5)

Guidance literature:

In benzene-d6; Cr-complex was heated in neat benzene-d6 at 170°C; rate consts. are given; (1)H NMR analysis of reaction mixt.; Kinetics;

Reference yield:

(1,3-diphenylpropane)bis(tricarbonylchromium) (108319-36-4) + benzene-d6 (1076-43-3) → (benzene-d6)tricarbonylchromium (38095-88-4) + (1,3-diphenylpropane)tricarbonylchromium (82066-92-0)

Guidance literature:

In benzene-d6; Cr-complex was heated in neat benzene-d6 at 170°C; rate consts. are given; (1)H NMR analysis of reaction mixt.; Kinetics;

upstream raw materials:

(1,3-diphenylpropane)bis(tricarbonylchromium)

benzene-d6

(1,4-diphenylbutane)bis(tricarbonylchromium)

{4-(trideuteriomethyl)-4'-methyl-α,α-dideuteriodiphenylmethane}tricarbonylchromium

Downstream raw materials:

d₅-n-butylbenzene

Refernces

• 1、 Traylor, Teddy G.,Goldberg, Martin J.. "Stereoelectronic effects in arene exchange of (arene)tricarbonylchromium complexes: Internal arene exchange and internal arene catalysis of external arene exchange". . p. 2413 - 2416. Retrieved 2008/10/08.