10-acetoxy-10-[7-methoxy-3-(2-N,N-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one

Base Information

Chemical Name:10-acetoxy-10-[7-methoxy-3-(2-N,N-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one
CAS No.:662723-20-8
Molecular Formula:C₃₃H₂₇NO₅
Molecular Weight:517.581
Hs Code.:

Synonyms:10-acetoxy-10-[7-methoxy-3-(2-N,N-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one

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Chemical Property of 10-acetoxy-10-[7-methoxy-3-(2-N,N-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one

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Technology Process of 10-acetoxy-10-[7-methoxy-3-(2-N,N-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one

There total 12 articles about 10-acetoxy-10-[7-methoxy-3-(2-N,N-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 64-19-7,77671-22-8
acetic acid

: 662723-16-2
10-hydroxy-10-[7-methoxy-3-(2-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one

: 662723-20-8
10-acetoxy-10-[7-methoxy-3-(2-N,N-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one

Guidance literature:: With dmap; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; In dichloromethane; at 0 ℃;

Reference yield:

: 612-14-6
phthalyl alcohol

: 662723-20-8
10-acetoxy-10-[7-methoxy-3-(2-N,N-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one

Guidance literature:: Multi-step reaction with 12 steps

1: 62 percent / NaH / tetrahydrofuran / 0 - 20 °C

2: tetrabutylammonium bromide; aq. NaClO / ethyl acetate / 0 - 20 °C

3: 44.6 g / tetrahydrofuran / 0.5 h / 0 °C

4: 87 percent / CrO₃; aq. H₂SO₄ / acetone / 0 - 20 °C

5: 73 percent / Zn / tetrahydrofuran / 0.5 h / Heating

6: 81 percent / triethylamine; methanesulfonyl chloride / CH₂Cl₂ / 2 h / 0 °C

7: 52 percent / EtMgBr / tetrahydrofuran; CH₂Cl₂ / Heating

8: 80 percent / K₂CO₃ / methanol / 4 h / 20 °C

9: MnO₂ / benzene / 2 h / 20 °C

10: 662 mg / 2-methyl-2-butene; NaClO₂; NaH₂PO₄*H₂O / 2-methyl-propan-2-ol; H₂O / 2 h / 20 °C

11: 81 percent / N,N-diisopropylethylamine; dicyano diethylphosphate / tetrahydrofuran / 2 h / 0 °C

12: 82 percent / DMAP; EDC / CH₂Cl₂ / 0 °C

With chromium(VI) oxide; dmap; manganese(IV) oxide; sodium hypochlorite; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; dicyano diethylphosphate; sulfuric acid; ethylmagnesium bromide; tetrabutylammomium bromide; sodium hydride; potassium carbonate; methanesulfonyl chloride; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; triethylamine; N-ethyl-N,N-diisopropylamine; zinc; In tetrahydrofuran; methanol; dichloromethane; water; ethyl acetate; acetone; tert-butyl alcohol; benzene;

Reference yield:

: 180713-44-4
2-[(pivaloyloxy)methyl]benzaldehyde

: 662723-20-8
10-acetoxy-10-[7-methoxy-3-(2-N,N-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one

Guidance literature:: Multi-step reaction with 10 steps

1: 44.6 g / tetrahydrofuran / 0.5 h / 0 °C

2: 87 percent / CrO₃; aq. H₂SO₄ / acetone / 0 - 20 °C

3: 73 percent / Zn / tetrahydrofuran / 0.5 h / Heating

4: 81 percent / triethylamine; methanesulfonyl chloride / CH₂Cl₂ / 2 h / 0 °C

5: 52 percent / EtMgBr / tetrahydrofuran; CH₂Cl₂ / Heating

6: 80 percent / K₂CO₃ / methanol / 4 h / 20 °C

7: MnO₂ / benzene / 2 h / 20 °C

8: 662 mg / 2-methyl-2-butene; NaClO₂; NaH₂PO₄*H₂O / 2-methyl-propan-2-ol; H₂O / 2 h / 20 °C

9: 81 percent / N,N-diisopropylethylamine; dicyano diethylphosphate / tetrahydrofuran / 2 h / 0 °C

10: 82 percent / DMAP; EDC / CH₂Cl₂ / 0 °C

With chromium(VI) oxide; dmap; manganese(IV) oxide; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; dicyano diethylphosphate; sulfuric acid; ethylmagnesium bromide; potassium carbonate; methanesulfonyl chloride; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; triethylamine; N-ethyl-N,N-diisopropylamine; zinc; In tetrahydrofuran; methanol; dichloromethane; water; acetone; tert-butyl alcohol; benzene;