Carbamic acid, (2-methyl-3-nitrophenyl)-, methyl ester (9CI)

Base Information

• Chemical Name: Carbamic acid, (2-methyl-3-nitrophenyl)-, methyl ester (9CI)
• CAS No.: 817572-88-6
• Molecular Formula: C9H10 N2 O4
• Molecular Weight: 210.1867
• Mol file: 817572-88-6.mol

Synonyms:Carbamic acid, (2-methyl-3-nitrophenyl)-, methyl ester (9CI)

Chemical Property of Carbamic acid, (2-methyl-3-nitrophenyl)-, methyl ester (9CI)

Chemical Property:

• PSA: 84.15000
• LogP: 2.67770

Purity/Quality:

(2-METHYL-3-NITROPHENYL)CARBAMIC ACID METHYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbamic acid, (2-methyl-3-nitrophenyl)-, methyl ester (9CI)

There total 2 articles about Carbamic acid, (2-methyl-3-nitrophenyl)-, methyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,6-dinitrotoluene (606-20-2) + methyl chloroformate (79-22-1) → 2-nitro-6-methylcarbamoyl-toluene (817572-88-6)

Guidance literature:

methyl chloroformate; With zinc; In toluene; at 20 ℃; for 0.166667h;

2,6-dinitrotoluene; In toluene; at 20 ℃;

DOI:10.1002/adsc.200404151

Reference yield:

methanol (67-56-1) + carbon monoxide (201230-82-2) + 2,6-dinitrotoluene (606-20-2) → toluene-2,6-bis(methyl) carbamate (20913-18-2) + 2-amino-6-methylcarbamoyl-toluene + 2-nitro-6-methylcarbamoyl-toluene (817572-88-6)

Guidance literature:

With phenylphosphonate; 3-nitro-o-tolylamine; 2,2-dimethoxy-propane; {Pd([1,10]phenanthroline)2}[BF₄]2; at 170 ℃; for 5h; under 75006 Torr;

DOI:10.1002/adsc.200404151

Reference yield:

2-nitro-6-methylcarbamoyl-toluene (817572-88-6) → 2-amino-6-methylcarbamoyl-toluene

Guidance literature:

With sodium hydroxide; triiron dodecarbonyl; In tetrahydrofuran; water;

DOI:10.1002/adsc.200404151

upstream raw materials:

methanol

carbon monoxide

2,6-dinitrotoluene

methyl chloroformate

Refernces