formyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside

Base Information

• Chemical Name: formyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside
• CAS No.: 98854-00-3
• Molecular Formula: C₃₅H₂₈O₁₁
• Molecular Weight: 624.601
• Mol file: 98854-00-3.mol

Synonyms:formyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside

Chemical Property of formyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of formyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside

There total 1 articles about formyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

formic acid (64-18-6) + 2,3,4,6-tetra-O-Bz-β-D-glucopyranosyl bromide (165877-99-6) → formyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside (98854-00-3)

Guidance literature:

With silver nitrate; at 20 ℃; for 1h;

DOI:10.1021/jo0600510

Reference yield: 64.0%

formyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside (98854-00-3) → vinyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside (905918-05-0)

Guidance literature:

With pyridine; In tetrahydrofuran; toluene; at -78 - 0 ℃;

DOI:10.1021/jo0600510

Reference yield:

formyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside (98854-00-3) + allyl-trimethyl-silane (762-72-1) → 3-(2',3',4',6'-tetra-O-benzoyl-β-D-glucopyranosyl)-1-propene (98920-47-9) + 3-(2',3',4',6'-tetra-O-benzoyl-α-D-glucopyranosyl)-1-propene (98854-01-4)

Guidance literature:

With boron trifluoride diethyl etherate; In acetonitrile; at 65 ℃; for 4h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1016/S0040-4039(00)98529-0

upstream raw materials:

formic acid

2,3,4,6-tetra-O-Bz-β-D-glucopyranosyl bromide

Downstream raw materials:

3-(2',3',4',6'-tetra-O-benzoyl-β-D-glucopyranosyl)-1-propene

3-(2',3',4',6'-tetra-O-benzoyl-α-D-glucopyranosyl)-1-propene

vinyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside

(1'R,3'S)-2',2'-dichloro-3'-hydroxycyclobutyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside