deuterio-trimethyl-silane

Base Information

• Chemical Name: deuterio-trimethyl-silane
• CAS No.: 18026-91-0
• Molecular Formula: C₃H₁₀Si
• Molecular Weight: 75.19
• Mol file: 18026-91-0.mol

Synonyms:deuterio-trimethyl-silane

Chemical Property of deuterio-trimethyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of deuterio-trimethyl-silane

There total 2 articles about deuterio-trimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(Trimethylsilyloxy)cyclohexene (6651-36-1) → deuterio-trimethyl-silane (18026-91-0) + <2-D>Cyclohexanone (2979-36-4)

Guidance literature:

With deuterium; [RuCl(η²-H2)(dppe)2]OTf; In 1,2-dichloro-ethane; at 50 ℃; for 48h; under 760 Torr;

DOI:10.1016/S0022-328X(03)00470-4

Reference yield:

chloro-trimethyl-silane (75-77-4) + benzene-d6 (1076-43-3) → deuterio-trimethyl-silane (18026-91-0) + C9H9(2)H5Si (95450-75-2)

Guidance literature:

With calcium; Yield given. Multistep reaction. Yields of byproduct given; 1) 900 deg C, 0.005 Torr, 2) 1 h, r.t., 0.005 Torr;

DOI:10.1246/cl.1984.1989

Reference yield:

deuterio-trimethyl-silane (18026-91-0) → Monodeuteromethan (676-49-3)

Guidance literature:

With Fe⁺; under 1E-05 Torr; Rate constant;

DOI:10.1021/ja00076a046

upstream raw materials:

chloro-trimethyl-silane

benzene-d6

1-(Trimethylsilyloxy)cyclohexene

Downstream raw materials:

Monodeuteromethan

(Ph₃P)2IrH₂(dimethylformamide)2⁽¹⁺⁾

3-deuterio-1-phenylpropan-1-one