(S,S)-(+)-1-[(1-naphthyl)(4-methoxyphenyl)phosphino]-1'-[(1-naphthyl)((4-trifluoromethyl)phenyl)phosphino]ferrocene

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Chemical Name:(S,S)-(+)-1-[(1-naphthyl)(4-methoxyphenyl)phosphino]-1'-[(1-naphthyl)((4-trifluoromethyl)phenyl)phosphino]ferrocene
CAS No.:311820-13-0
Molecular Formula:C₄₄H₃₃F₃FeOP₂
Molecular Weight:752.535
Hs Code.:

Synonyms:(S,S)-(+)-1-[(1-naphthyl)(4-methoxyphenyl)phosphino]-1'-[(1-naphthyl)((4-trifluoromethyl)phenyl)phosphino]ferrocene

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Chemical Property of (S,S)-(+)-1-[(1-naphthyl)(4-methoxyphenyl)phosphino]-1'-[(1-naphthyl)((4-trifluoromethyl)phenyl)phosphino]ferrocene

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Technology Process of (S,S)-(+)-1-[(1-naphthyl)(4-methoxyphenyl)phosphino]-1'-[(1-naphthyl)((4-trifluoromethyl)phenyl)phosphino]ferrocene

There total 1 articles about (S,S)-(+)-1-[(1-naphthyl)(4-methoxyphenyl)phosphino]-1'-[(1-naphthyl)((4-trifluoromethyl)phenyl)phosphino]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 311820-19-6
(R)-(-)-Methyl (1-Naphthyl)(4-(trifluoromethyl)phenyl)phosphinite-Borane

: 311820-10-7
(S)-(+)-Methyl (1'-Bromo-1-ferrocenyl)-phenylphosphinite-Borane

: 311820-13-0
(S,S)-(+)-1-[(1-naphthyl)(4-methoxyphenyl)phosphino]-1'-[(1-naphthyl)((4-trifluoromethyl)phenyl)phosphino]ferrocene

Guidance literature:: With sec.-butyllithium; In tetrahydrofuran; diethyl ether; (Ar); standard Schlenk technique; Fe compd. dissolved in Et2O and THF; cooled to -70°C; sec-BuLi added after 1 h; soln. of methyl phosphinite-borane in THF transferred; mixt. warmed to ambient temp. for 15 h; H2O added; extd. (CH2Cl2); dried (MgSO4); filtered; concd.; chromd. (SiO2, CH2Cl2/hexane, 1/2); chromd. (alumina, CH2Cl2/hexane, 1/1); elem. anal.;
DOI:10.1021/om0004489

Reference yield:

: (acetylacetonato)dicarbonylrhodium (l)

: 311820-13-0
(S,S)-(+)-1-[(1-naphthyl)(4-methoxyphenyl)phosphino]-1'-[(1-naphthyl)((4-trifluoromethyl)phenyl)phosphino]ferrocene

: 1333-74-0
hydrogen

: 311820-32-3,311820-27-6,311820-31-2
[(C₅H₄(C₁₀H₇)P(C₆H₄CF₃))Fe(C₅H₄P(C₁₀H₇)(C₆H₄OCH₃))Rh(CO)2H]

Guidance literature:: With carbon monoxide; In cyclohexane; High Pressure; soln. of Rh complex and ligand in cyclohexane was degassed and introduced to IR autoclave; stirred soln. was pressurized with 18 bar of syngas (1/1 CO/H2); heated at 60°C; not isolated; IR monitoring;
DOI:10.1021/om0004489