Technology Process of (phenylimido)vanadium(V) trichloride
There total 1 articles about (phenylimido)vanadium(V) trichloride which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
octane;
byproducts: CO2; (N2) to VOCl3 in n-octane phenyl isocyanate was added, heated at 125°C overnight; react. mixt. was cooled, filtered through Celite and evapd., residue wasdissolved in hot n-hexane and cooled to -30°C; elem. anal.;
DOI:10.1021/ja100573d
- Guidance literature:
-
In
diethyl ether;
(N2); standard Schlenk technique; soln. of LiNEt2 (3.3 equiv.) added dropwise to stirred soln. of V(=NPh)Cl3 (1 equiv.) at 0°C; stirred for 16 h at room temp.; precipitate removed (centrifugation/decantation); supernatant soln. evapd. in vac.; residue extd. (hexane); hexane removed in vac.;
DOI:10.1021/ic991415s
- Guidance literature:
-
1,3-bis(2,6-diisopropylphenyl)imidazolin-2-imine;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -30 - 20 ℃;
for 3h;
Inert atmosphere;
(phenylimido)vanadium(V) trichloride;
In
toluene;
at -30 - 20 ℃;
for 12h;
Inert atmosphere;
DOI:10.1021/om500986m
