[(m,m'-(CF₃)2C₆H₃)-bis(imino)acenaphthene]platina-2,3,4,5-tetra(propyl)cyclopentadiene

Base Information

• Chemical Name: [(m,m'-(CF₃)2C₆H₃)-bis(imino)acenaphthene]platina-2,3,4,5-tetra(propyl)cyclopentadiene
• CAS No.: 870525-20-5
• Molecular Formula: C₄₄H₄₀F₁₂N₂Pt
• Molecular Weight: 1019.88
• Mol file: 870525-20-5.mol

Synonyms:[(m,m'-(CF₃)2C₆H₃)-bis(imino)acenaphthene]platina-2,3,4,5-tetra(propyl)cyclopentadiene

Chemical Property of [(m,m'-(CF₃)2C₆H₃)-bis(imino)acenaphthene]platina-2,3,4,5-tetra(propyl)cyclopentadiene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(m,m'-(CF₃)2C₆H₃)-bis(imino)acenaphthene]platina-2,3,4,5-tetra(propyl)cyclopentadiene

There total 1 articles about [(m,m'-(CF₃)2C₆H₃)-bis(imino)acenaphthene]platina-2,3,4,5-tetra(propyl)cyclopentadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

4-Octyne (1942-45-6) + (σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0) (701913-42-0) + hydrogen (1333-74-0) → [(m,m'-(CF3)2C6H3)-bis(imino)acenaphthene]platina-2,3,4,5-tetra(propyl)cyclopentadiene (870525-20-5)

Guidance literature:

In tetrahydrofuran; (N2) addn. of platinum complex to a soln. of alkyne in THF, addn. of H2 for 3 min, heating to 60°C for 60 min, cooling to room temp.; evapn., addn. of pentane, sepn., drying ppt. in vac.;

DOI:10.1021/ja052729j

upstream raw materials:

4-Octyne

(σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0)

hydrogen