1,1,2-Triphenylpropane

Base Information

• Chemical Name: 1,1,2-Triphenylpropane
• CAS No.: 94871-36-0
• Molecular Formula: C₂₁H₂₀
• Molecular Weight: 272.39
• UNII: 422S8K63ST
• DSSTox Substance ID: DTXSID7036666
• Nikkaji Number: J2.788.252H
• Wikidata: Q27115761
• Mol file: 94871-36-0.mol

Synonyms:1,1,2-Triphenylpropane;94871-36-0;422S8K63ST;1,1,2-Triphenylpropane, (+/-)-;UNII-422S8K63ST;1,1',1''-(1-Methyl-1-ethanyl-2-ylidene)tris(benzene);Benzene, 1,1',1''-(1-methyl-1-ethanyl-2-ylidene)tris-;(1,2-diphenylpropyl)benzene;DTXSID7036666;CHEBI:34028;(+/-)-1,1,2-triphenylpropane;AKOS024324938;Q27115761

Chemical Property of 1,1,2-Triphenylpropane

Chemical Property:

• XLogP3: 5.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 272.156500638
• Heavy Atom Count: 21
• Complexity: 258

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C1=CC=CC=C1)C(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of 1,1,2-Triphenylpropane

There total 26 articles about 1,1,2-Triphenylpropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

Diphenylmethane (101-81-5) + (+/-)-1-phenylethyl diphenyl phosphate (76263-88-2) → 1,1,2-Triphenylpropane (94871-36-0)

Guidance literature:

Diphenylmethane; With n-butyllithium; In tetrahydrofuran; hexane; at 0 - 15 ℃; for 0.25h;

(+/-)-1-phenylethyl diphenyl phosphate; In tetrahydrofuran; hexane; at -15 ℃; for 0.25h;

DOI:10.1016/j.tet.2019.03.050

Reference yield: 87.0%

Diphenylmethane (101-81-5) + (+/-)-1-phenylethyl diethyl phosphate (34881-06-6) → 1,1,2-Triphenylpropane (94871-36-0)

Guidance literature:

Diphenylmethane; With n-butyllithium; In tetrahydrofuran; hexane; at 0 - 15 ℃; for 0.25h;

(+/-)-1-phenylethyl diethyl phosphate; In tetrahydrofuran; hexane; at -15 ℃; for 0.25h;

DOI:10.1016/j.tet.2019.03.050

Reference yield: 83.0%

1,1,2-triphenylprop-1-ene (3677-70-1) → 1,1,2-Triphenylpropane (94871-36-0)

Guidance literature:

With C₇H₁₄N₃⁽¹⁺⁾*Cl^(1-); sodium triethylborohydride; cobalt(II) chloride; In tetrahydrofuran; at 120 ℃; for 16h; under 37503.8 Torr; Autoclave;

DOI:10.1021/acs.organomet.0c00498

upstream raw materials:

di-tert-butyl peroxide

Diphenylmethane

2,3-diphenyl-1H-inden-1-one

1,1,2-triphenylprop-1-ene

Downstream raw materials:

phenylacetic acid

1,1'-ethylidenebis-benzene

2,2-diphenylpropanoic acid

toluene