(S)-2-(1-(4-fluorophenyl)ethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:(S)-2-(1-(4-fluorophenyl)ethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:1189119-96-7
Molecular Formula:C₁₄H₂₀BFO₂
Molecular Weight:250.121
Hs Code.:

Synonyms:(S)-2-(1-(4-fluorophenyl)ethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Chemical Property of (S)-2-(1-(4-fluorophenyl)ethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Technology Process of (S)-2-(1-(4-fluorophenyl)ethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 9 articles about (S)-2-(1-(4-fluorophenyl)ethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 405-99-2
para-fluorostyrene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1189119-96-7
(S)-2-(1-(4-fluorophenyl)ethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; With copper(l) chloride; sodium t-butanolate; (1S,1S',2R,2R')-1,1'-di-tert-butyl-(2,2’)-diphospholane; In toluene; for 0.166667h; Inert atmosphere;

para-fluorostyrene; In toluene; at 22 ℃; for 24h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/anie.200902015

Reference yield: 80.0%

: 1189119-96-7
(S)-2-(1-(4-fluorophenyl)ethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With ImPPA; cobalt(II) acetate; In diethyl ether; at 20 ℃; for 18h; Schlenk technique; Inert atmosphere;

Reference yield: 5.0%

: 1416982-23-4
(S)-1-(4-fluorophenyl)-N,N,N-trimethylethanaminium trifluoromethanesulfonate

: 73183-34-3
bis(pinacol)diborane

: 1189119-96-7
(R)-2-(1-(4-fluorophenyl)ethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With bis(1,5-cyclooctadiene)nickel⁽⁰⁾; sodium methylate; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 6h; enantiospecific reaction;
DOI:10.1021/acs.orglett.5b03455