{2,2-Dimethyl-1-[1-phenyl-meth-(Z)-ylidene]-propoxy}-trimethyl-silane

Base Information

• Chemical Name: {2,2-Dimethyl-1-[1-phenyl-meth-(Z)-ylidene]-propoxy}-trimethyl-silane
• CAS No.: 82027-26-7
• Molecular Formula: C₁₅H₂₄OSi
• Molecular Weight: 248.44
• Mol file: 82027-26-7.mol

Synonyms:{2,2-Dimethyl-1-[1-phenyl-meth-(Z)-ylidene]-propoxy}-trimethyl-silane

Chemical Property of {2,2-Dimethyl-1-[1-phenyl-meth-(Z)-ylidene]-propoxy}-trimethyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {2,2-Dimethyl-1-[1-phenyl-meth-(Z)-ylidene]-propoxy}-trimethyl-silane

There total 1 articles about {2,2-Dimethyl-1-[1-phenyl-meth-(Z)-ylidene]-propoxy}-trimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro-trimethyl-silane (75-77-4) + tert-butyl benzyl ketone (6721-67-1) → {2,2-Dimethyl-1-[1-phenyl-meth-(Z)-ylidene]-propoxy}-trimethyl-silane (82027-26-7)

Guidance literature:

With lithium diisopropyl amide; Yield given. Multistep reaction; 1.) THF, ether, -78 deg C, 2.) reflux, 30 min;

DOI:10.1021/ja00379a018

Reference yield: 96.0%

{2,2-Dimethyl-1-[1-phenyl-meth-(Z)-ylidene]-propoxy}-trimethyl-silane (82027-26-7) → 3,3-Dimethyl-1-phenyl-1-trimethylsilanyloxy-butan-2-one (82027-27-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -10 ℃; for 2h;

DOI:10.1021/ja00379a018

Reference yield:

{2,2-Dimethyl-1-[1-phenyl-meth-(Z)-ylidene]-propoxy}-trimethyl-silane (82027-26-7) → Methanesulfonic acid 3,3-dimethyl-2-oxo-1-phenyl-butyl ester (82044-29-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 96 percent / 85percent m-chloroperbenzoic acid / CH₂Cl₂ / 2 h / -10 °C

2: 524 mg / CF₃COOH / methanol / 4 h / Heating

3: Et₃N

With triethylamine; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; In methanol; dichloromethane;

DOI:10.1021/ja00379a018

upstream raw materials:

chloro-trimethyl-silane

tert-butyl benzyl ketone

Downstream raw materials:

3,3-Dimethyl-1-phenyl-1-trimethylsilanyloxy-butan-2-one

α-hydroxy-1-neopentyl phenyl ketone

1-hydroxy-3,3-dimethyl-1-phenyl-butan-2-one

Methanesulfonic acid 3,3-dimethyl-2-oxo-1-phenyl-butyl ester