Ru(triphos)(CO)(H)2

Base Information

• Chemical Name: Ru(triphos)(CO)(H)2
• CAS No.: 115565-11-2
• Molecular Formula: C₄₂H₄₁OP₃Ru
• Molecular Weight: 755.778

Synonyms:Ru(triphos)(CO)(H)2

Chemical Property of Ru(triphos)(CO)(H)2

Chemical Property:

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Technology Process of Ru(triphos)(CO)(H)2

There total 12 articles about Ru(triphos)(CO)(H)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

tris(2,4-pentanedionato)ruthenium(III) (31378-26-4,31378-27-5,14284-93-6) + [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] (22031-12-5) → dihydridocarbonyl(1,1,1-tris(diphenylphosphinomethyl)ethane)ruthenium(II) complex (115565-11-2)

Guidance literature:

In methanol; isopropyl alcohol; at 140 ℃; under 22502.3 Torr; Autoclave;

DOI:10.1002/cctc.201701450

Reference yield: 84.0%

tris(2,4-pentanedionato)ruthenium(III) (31378-26-4,31378-27-5,14284-93-6) + hydrogen (1333-74-0) + propionaldehyde (123-38-6) + [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] (22031-12-5) → dihydridocarbonyl(1,1,1-tris(diphenylphosphinomethyl)ethane)ruthenium(II) complex (115565-11-2)

Guidance literature:

In neat (no solvent); High Pressure; stainless steel reactor with Ru-complex and triphos-compound under Ar propanal was added, ressurized with 120 bar of H2, stirred for 20 h at 150°C, cooled to 0°C; transfered into a Schlenk flask and ethanol was added, filtered, washed with ethanol twice; elem. anal.;

DOI:10.1021/ja2034377

Reference yield: 66.0%

Ru(CO3)(CO){CH3C(CH2PPh2)3-κ3P} + hydrogen (1333-74-0) → dihydridocarbonyl(1,1,1-tris(diphenylphosphinomethyl)ethane)ruthenium(II) complex (115565-11-2)

Guidance literature:

In tetrahydrofuran; at 100 ℃; for 2h; under 15001.5 Torr; High pressure;

DOI:10.1021/cs502025t

upstream raw materials:

propanoic acid methyl ester

[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]

K[(MeC(CH₂PPh₂)3)Ru(H)3]

carbon monoxide

Downstream raw materials:

[(1,1,1-tris(diphenylphosphinomethyl)ethane)Ru(CO)H(H₂)]⁽¹⁺⁾

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