4,4,6,6-tetrachloro-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine

Base Information

• Chemical Name: 4,4,6,6-tetrachloro-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine
• CAS No.: 1227724-63-1
• Molecular Formula: C₁₃H₁₁Cl₄N₄OP₃
• Molecular Weight: 473.99
• Mol file: 1227724-63-1.mol

Synonyms:4,4,6,6-tetrachloro-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine

Chemical Property of 4,4,6,6-tetrachloro-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4,6,6-tetrachloro-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine

There total 1 articles about 4,4,6,6-tetrachloro-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

2-((phenylamino)methyl)phenol (3526-45-2) → 4,4,6,6-tetrachloro-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine (1227724-63-1)

Guidance literature:

With 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine; triethylamine; In tetrahydrofuran; at 20 ℃; for 12h;

DOI:10.1016/j.poly.2010.02.002

Reference yield: 97.0%

pyrrolidine (123-75-1) + 4,4,6,6-tetrachloro-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine (1227724-63-1) → 4,4,6,6-tetrapyrrolidino-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine (1227724-66-4)

Guidance literature:

With triethylamine; In toluene; for 0.25h; Microwave irradiation; Reflux;

DOI:10.1016/j.poly.2010.02.002

Reference yield: 85.0%

morpholine (110-91-8,99108-56-2) + 4,4,6,6-tetrachloro-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine (1227724-63-1) → 4,4,6,6-tetramorpholino-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine (1227724-70-0)

Guidance literature:

With triethylamine; In toluene; for 0.5h; Microwave irradiation; Reflux;

DOI:10.1016/j.poly.2010.02.002

upstream raw materials:

2-((phenylamino)methyl)phenol

Downstream raw materials:

6,6-dichloro-4,4-di(pyrrolidino)-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine

4,4,6,6-tetrapyrrolidino-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine

6,6-dichloro-4,4-di(morpholino)-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine

4,4,6,6-tetramorpholino-3-phenyl-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine][2λ5,4λ5,6λ5][1,3,5,2,4,6]triazatriphosphorine