(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*(CO)4MnCOCH(C₆H₅)OCO^(1-)=(C₆H₅)3PNP(C₆H₅)3(CO)4MnCOCH(C₆H₅)OCO

Base Information

• Chemical Name: (C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*(CO)4MnCOCH(C₆H₅)OCO^(1-)=(C₆H₅)3PNP(C₆H₅)3(CO)4MnCOCH(C₆H₅)OCO
• CAS No.: 68433-31-8
• Molecular Formula: C₁₃H₆MnO₇*C₃₆H₃₀NP₂
• Molecular Weight: 867.713

Synonyms:(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*(CO)4MnCOCH(C₆H₅)OCO^(1-)=(C₆H₅)3PNP(C₆H₅)3(CO)4MnCOCH(C₆H₅)OCO

Chemical Property of (C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*(CO)4MnCOCH(C₆H₅)OCO^(1-)=(C₆H₅)3PNP(C₆H₅)3(CO)4MnCOCH(C₆H₅)OCO

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Technology Process of (C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*(CO)4MnCOCH(C₆H₅)OCO^(1-)=(C₆H₅)3PNP(C₆H₅)3(CO)4MnCOCH(C₆H₅)OCO

There total 1 articles about (C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*(CO)4MnCOCH(C₆H₅)OCO^(1-)=(C₆H₅)3PNP(C₆H₅)3(CO)4MnCOCH(C₆H₅)OCO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

(CO)5MnCOCOC6H5 + bis(triphenylphosphine)iminium chloride (21050-13-5) → (C6H5)3PNP(C6H5)3(1+)*(CO)4MnCOCH(C6H5)OCO(1-)=(C6H5)3PNP(C6H5)3(CO)4MnCOCH(C6H5)OCO (68433-31-8)

Guidance literature:

With Li(C₂H₅)3BH; In tetrahydrofuran; dichloromethane; to a stirred soln. of complex in THF was added Li(Et3BH) in THF, after 15 min a soln. of (Ph3PNPPh3)Cl in CH2Cl2 was added; the soln. was stirred for 10 min (N2 atm.); evapd. at room temp., extd. with ether, concd. and cooled at 0°Cfor 12 h; ppt. was washed with cold ether and extd. with THF, filtered,evapd.; elem. anal.;

DOI:10.1021/ja00267a015

Reference yield: 79.0%

(C6H5)3PNP(C6H5)3(1+)*(CO)4MnCOCH(C6H5)OCO(1-)=(C6H5)3PNP(C6H5)3(CO)4MnCOCH(C6H5)OCO (68433-31-8) → bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5) + 1-benzylidene-2-(2,4-dinitrophenyl)hydrazone (1157-84-2)

Guidance literature:

In tetrahydrofuran; soln. of complex in THF was refluxed for 6 days, cooled to room temp. (N2 atm.); cooled at -20°C for 2 h; ppt. was filtered, C6H5CHO was in the filtrate;

DOI:10.1021/ja00267a015

Reference yield: 70.0%

chloro-trimethyl-silane (75-77-4) + (C6H5)3PNP(C6H5)3(1+)*(CO)4MnCOCH(C6H5)OCO(1-)=(C6H5)3PNP(C6H5)3(CO)4MnCOCH(C6H5)OCO (68433-31-8) → (CO)5MnCOCH(C6H5)OSi(CH3)3 (68433-32-9)

Guidance literature:

In tetrahydrofuran; byproducts: PPNCl; to a stirred soln. of complex in THF was added Me3SiCl, the soln. was stirred for 4 h (N2 atm.); vac.-evapd. at room temp., chromy. on silica gel with hexane-ethyl acetate; crystd. upon evapn.; elem. anal.;

DOI:10.1021/ja00267a015

upstream raw materials:

bis(triphenylphosphine)iminium chloride

Downstream raw materials:

(CO)5MnCOCH(C₆H₅)OSi(CH₃)3

bis(triphenylphosphineiminium) pentacarbonylmanganate^(1-)

1-benzylidene-2-(2,4-dinitrophenyl)hydrazone

(CO)5MnCH(C₆H₅)OSi(CH₃)3

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