3-Chloro-2-trimethylsiloxypropene

Base Information

• Chemical Name: 3-Chloro-2-trimethylsiloxypropene
• CAS No.: 76634-95-2
• Molecular Formula: C6H13 Cl O Si
• Molecular Weight: 164.707
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID90503217
• Nikkaji Number: J47.918G
• Wikidata: Q63398316
• Mol file: 76634-95-2.mol

Synonyms:76634-95-2;3-CHLORO-2-TRIMETHYLSILOXYPROPENE;3-chloroprop-1-en-2-yloxy(trimethyl)silane;Silane,[[1-(chloromethyl)ethenyl]oxy]trimethyl-;[(3-CHLOROPROP-1-EN-2-YL)OXY]TRIMETHYLSILANE;SCHEMBL2421580;DTXSID90503217;AKOS006271819;[(3-Chloroprop-1-en-2-yl)oxy](trimethyl)silane;Q63398316

Chemical Property of 3-Chloro-2-trimethylsiloxypropene

Chemical Property:

• PSA: 9.23000
• LogP: 2.59040
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 164.0424193
• Heavy Atom Count: 9
• Complexity: 106

Purity/Quality:

99% ^*data from raw suppliers

3-CHLORO-2-TRIMETHYLSILOXYPROPENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)OC(=C)CCl

Technology Process of 3-Chloro-2-trimethylsiloxypropene

There total 6 articles about 3-Chloro-2-trimethylsiloxypropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro-trimethyl-silane (75-77-4) + chloroacetone (78-95-5) → chloro-1-trimethylsiloxy-2-propene (108574-30-7) + 3-chloro-2-(trimethylsilyloxy)prop-1-ene (76634-95-2)

Guidance literature:

With triethylamine; sodium iodide; In acetonitrile; at 20 ℃; for 21h; Yield given. Yields of byproduct given;

Reference yield:

trimethylsilyl iodide (16029-98-4) + chloroacetone (78-95-5) → 1-chloro-2-{(trimethylsilyl)oxy}propene (82319-13-9) + 3-chloro-2-(trimethylsilyloxy)prop-1-ene (76634-95-2)

Guidance literature:

With 1,1,1,3,3,3-hexamethyl-disilazane; In tetrachloromethane; at 20 ℃; for 0.5h; Yield given. Yields of byproduct given;

Reference yield:

2-(Trimethylsilyloxy)propene (1833-53-0) → 1-(2-Chloro-1-methyl-1-trimethylsilanyloxy-ethyl)-pyrrolidine-2,5-dione (108709-28-0) + 1-chloro-2-{(trimethylsilyl)oxy}propene (82319-13-9) + 3-chloro-2-(trimethylsilyloxy)prop-1-ene (76634-95-2)

Guidance literature:

With N-chloro-succinimide; In dichloromethane; Heating;

DOI:10.1016/S0040-4039(00)84585-2

upstream raw materials:

N-chloro-succinimide

2-(Trimethylsilyloxy)propene

3-chloro-1-trimethylsilyl-2-propanone

chloro-trimethyl-silane

Downstream raw materials:

n-pentyl methyl ketone

2-Methyl-6-(2-oxopropyl)cyclohexanone

2-methyl-2-(2-oxopropyl)cyclohexanone

2-(2-oxopropyl)cyclohexanone