trans-(C₆F₅)(Ph₂P)2(CH₂)16PtCl

Base Information

Chemical Name:trans-(C₆F₅)(Ph₂P)2(CH₂)16PtCl
CAS No.:945679-48-1
Molecular Formula:C₄₆H₅₂ClF₅P₂Pt
Molecular Weight:992.391
Hs Code.:

trans-(C<sub>6</sub>F<sub>5</sub>)(Ph<sub>2</sub>P)2(CH<sub>2</sub>)16PtCl

Synonyms:trans-(C₆F₅)(Ph₂P)2(CH₂)16PtCl

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Chemical Property of trans-(C₆F₅)(Ph₂P)2(CH₂)16PtCl

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Technology Process of trans-(C₆F₅)(Ph₂P)2(CH₂)16PtCl

There total 1 articles about trans-(C₆F₅)(Ph₂P)2(CH₂)16PtCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 936553-09-2
trans-[(C₆F₅)(Ph₂P(CH₂)7CH=CH₂)2PtCl]

: 1333-74-0
hydrogen

: 945679-48-1
trans-(C₆F₅)(Ph₂P)2(CH₂)16PtCl

Guidance literature:: With Pd/C; Grubbs catalyst first generation; In not given; 1. 5-7 mol% Grubbs' Catalyst; 2. 10% Pd/C, 1 atm of H2;
DOI:10.1021/ja071612n

Reference yield: 79.0%

: 945679-48-1
trans-(C₆F₅)(Ph₂P)2(CH₂)16PtCl

: 72965-79-8
(trimethylsilyl)(trimethylstannyl)butadiyne

: 945679-46-9
trans-(C₆F₅)(Ph₂P)2(CH₂)16Pt(C₂)2SiMe₃

Guidance literature:: With KPF₆; copper(l) iodide; In methanol; dichloromethane; a Schlenk flask was charged with Pt-complex, (CH3)3SnC4Si(CH3)3, CuI, KPF6, CH2Cl2 and methanol with stirring, 16 h; the solvent was removed by oil pump vac., the residue was chromd. on an alumina column (90:10 v/v hexanes/CH2Cl2), the solvent was removed by oil pump vac.; elem. anal.;
DOI:10.1021/ja071612n