3-azido-N-tert-butyldimethylsiloxy-N-tert-butylaminobenzene

Base Information

Chemical Name:3-azido-N-tert-butyldimethylsiloxy-N-tert-butylaminobenzene
CAS No.:749916-98-1
Molecular Formula:C₁₆H₂₈N₄OSi
Molecular Weight:320.51
Hs Code.:

Synonyms:3-azido-N-tert-butyldimethylsiloxy-N-tert-butylaminobenzene

Suppliers and Price of 3-azido-N-tert-butyldimethylsiloxy-N-tert-butylaminobenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-azido-N-tert-butyldimethylsiloxy-N-tert-butylaminobenzene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-azido-N-tert-butyldimethylsiloxy-N-tert-butylaminobenzene

There total 3 articles about 3-azido-N-tert-butyldimethylsiloxy-N-tert-butylaminobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 233584-39-9
N-3-bromophenyl-N-tert-butyl-N-tert-butyldimethylsiloxyamine

: 749916-98-1
3-azido-N-tert-butyldimethylsiloxy-N-tert-butylaminobenzene

Guidance literature:: N-3-bromophenyl-N-tert-butyl-N-tert-butyldimethylsiloxyamine; With n-butyllithium; In diethyl ether; hexane; at -78 - 20 ℃; for 1.25h;

With 4-toluenesulfonyl azide; In diethyl ether; hexane; at 20 ℃;
DOI:10.1021/jo049500r

Reference yield:

: 108-36-1
1,3-dibromobenzene

: 749916-98-1
3-azido-N-tert-butyldimethylsiloxy-N-tert-butylaminobenzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: BuLi

2.1: n-BuLi / diethyl ether; hexane / 1.25 h / -78 - 20 °C

2.2: 83 percent / tosyl azide / diethyl ether; hexane / 20 °C

With n-butyllithium; In diethyl ether; hexane;
DOI:10.1021/jo049500r

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 749916-98-1
3-azido-N-tert-butyldimethylsiloxy-N-tert-butylaminobenzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: BuLi

2.1: n-BuLi / diethyl ether; hexane / 1.25 h / -78 - 20 °C

2.2: 83 percent / tosyl azide / diethyl ether; hexane / 20 °C

With n-butyllithium; In diethyl ether; hexane;
DOI:10.1021/jo049500r