(E)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene

Base Information

Chemical Name:(E)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene
CAS No.:1422374-68-2
Molecular Formula:C₁₆H₁₂ClF₃OS
Molecular Weight:344.785
Hs Code.:

Synonyms:(E)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene

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Chemical Property of (E)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene

Chemical Property:

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Technology Process of (E)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene

There total 2 articles about (E)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 455-19-6
4-Trifluoromethylbenzaldehyde

: 24824-93-9
chloromethyl p-tolyl sulfoxide

: 1422374-68-2
(E)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene

: (Z)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene

Guidance literature:: chloromethyl p-tolyl sulfoxide; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 0.25h; Inert atmosphere;

With diethyl chlorophosphate; In tetrahydrofuran; hexane; at -78 - -60 ℃; for 0.25h; Inert atmosphere;

4-Trifluoromethylbenzaldehyde; In tetrahydrofuran; hexane; at -60 - 0 ℃; for 0.5h; Overall yield = 93%; Inert atmosphere;
DOI:10.1002/hc.21395

Reference yield:

: 24824-93-9
chloromethyl p-tolyl sulfoxide

: 104-88-1
4-chlorobenzaldehyde

: 1422374-68-2
(E)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene

: (Z)-1-chloro-4-[2-chloro-2-(p-tolylsulfinyl)vinyl]benzene

Guidance literature:: chloromethyl p-tolyl sulfoxide; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 0.25h; Inert atmosphere;

With diethyl chlorophosphate; In tetrahydrofuran; hexane; at -78 - -60 ℃; for 0.25h; Inert atmosphere;

4-chlorobenzaldehyde; In tetrahydrofuran; hexane; at -60 - 0 ℃; for 0.5h; Overall yield = 90%; Inert atmosphere;
DOI:10.1002/hc.21395

Reference yield: 56.0%

: 1422374-68-2
(E)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene

: 536-74-3
phenylacetylene

: 1422374-88-6
(Z)-(3-(4-(trifluoromethyl)phenyl)hexa-3-en-1,5-diyne-1,6-diyl)dibenzene

Guidance literature:: phenylacetylene; With n-butyllithium; In tetrahydrofuran; at 20 ℃; for 0.0333333h; Inert atmosphere;

(E)-1-({1-chloro-2-[4-(trifluoromethyl)phenyl]vinyl}sulfinyl)-4-methylbenzene; In tetrahydrofuran; at 20 ℃; for 0.5h;
DOI:10.1016/j.tetlet.2012.11.152