(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester

Base Information

Chemical Name:(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester
CAS No.:1449522-85-3
Molecular Formula:C₂₅H₃₁BrO₄
Molecular Weight:475.423
Hs Code.:

Synonyms:(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester

Suppliers and Price of (-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester

There total 4 articles about (-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1449522-84-2
2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-hydroxyallyl]hexyl ester

: 2746-25-0
p-Methoxybenzyl bromide

: 1449522-85-3
(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester

Guidance literature:: With potassium hexamethylsilazane; triethylamine; In tetrahydrofuran; toluene; at -78 - 20 ℃; for 1.5h; Inert atmosphere;
DOI:10.1016/j.tetlet.2013.07.038

Reference yield:

: 1449522-82-0
(3R,4S)-3-benzoyloxynon-1-en-4-ol

: 1449522-85-3
(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride / dichloromethane; tetrahydrofuran; mineral oil / 2.5 h / Inert atmosphere; Reflux

2: potassium carbonate / methanol / 18 h / 20 - 50 °C / Inert atmosphere

3: potassium hexamethylsilazane; triethylamine / tetrahydrofuran; toluene / 1.5 h / -78 - 20 °C / Inert atmosphere

With potassium hexamethylsilazane; sodium hydride; potassium carbonate; triethylamine; In tetrahydrofuran; methanol; dichloromethane; toluene; mineral oil;
DOI:10.1016/j.tetlet.2013.07.038

Reference yield:

: 1449522-83-1
(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-benzoyloxyallyl]hexyl ester

: 1449522-85-3
(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / methanol / 18 h / 20 - 50 °C / Inert atmosphere

2: potassium hexamethylsilazane; triethylamine / tetrahydrofuran; toluene / 1.5 h / -78 - 20 °C / Inert atmosphere

With potassium hexamethylsilazane; potassium carbonate; triethylamine; In tetrahydrofuran; methanol; toluene;
DOI:10.1016/j.tetlet.2013.07.038