(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-benzoyloxyallyl]hexyl ester

Base Information

Chemical Name:(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-benzoyloxyallyl]hexyl ester
CAS No.:1449522-83-1
Molecular Formula:C₂₄H₂₇BrO₄
Molecular Weight:459.38
Hs Code.:

Synonyms:(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-benzoyloxyallyl]hexyl ester

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Chemical Property of (-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-benzoyloxyallyl]hexyl ester

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Technology Process of (-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-benzoyloxyallyl]hexyl ester

There total 1 articles about (-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-benzoyloxyallyl]hexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1449522-82-0
(3R,4S)-3-benzoyloxynon-1-en-4-ol

: 535961-79-6
2-bromo-6-methylbenzoyl chloride

: 1449522-83-1
(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-benzoyloxyallyl]hexyl ester

Guidance literature:: With sodium hydride; In tetrahydrofuran; dichloromethane; mineral oil; for 2.5h; Inert atmosphere; Reflux;
DOI:10.1016/j.tetlet.2013.07.038

Reference yield: 93.0%

: 1449522-83-1
(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-benzoyloxyallyl]hexyl ester

: 1449522-84-2
2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-hydroxyallyl]hexyl ester

Guidance literature:: With potassium carbonate; In methanol; at 20 - 50 ℃; for 18h; Inert atmosphere;
DOI:10.1016/j.tetlet.2013.07.038

Reference yield:

: 1449522-83-1
(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-benzoyloxyallyl]hexyl ester

: 1449522-85-3
(-)-2-bromo-6-methylbenzoic acid (S)-1-[(R)-1-(4-methoxybenzyloxy)allyl]hexyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / methanol / 18 h / 20 - 50 °C / Inert atmosphere

2: potassium hexamethylsilazane; triethylamine / tetrahydrofuran; toluene / 1.5 h / -78 - 20 °C / Inert atmosphere

With potassium hexamethylsilazane; potassium carbonate; triethylamine; In tetrahydrofuran; methanol; toluene;
DOI:10.1016/j.tetlet.2013.07.038