(E)-1-(allyloxy)-3-(3,4-dimethoxyphenyl)-1-oxopropan-2-yl 3-(3,4-bis(tert-butyldimethylsilyloxy)phenyl)acrylate

Base Information

Chemical Name:(E)-1-(allyloxy)-3-(3,4-dimethoxyphenyl)-1-oxopropan-2-yl 3-(3,4-bis(tert-butyldimethylsilyloxy)phenyl)acrylate
CAS No.:1430417-23-4
Molecular Formula:C₃₅H₅₂O₈Si₂
Molecular Weight:656.964
Hs Code.:

Synonyms:(E)-1-(allyloxy)-3-(3,4-dimethoxyphenyl)-1-oxopropan-2-yl 3-(3,4-bis(tert-butyldimethylsilyloxy)phenyl)acrylate

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Chemical Property of (E)-1-(allyloxy)-3-(3,4-dimethoxyphenyl)-1-oxopropan-2-yl 3-(3,4-bis(tert-butyldimethylsilyloxy)phenyl)acrylate

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Technology Process of (E)-1-(allyloxy)-3-(3,4-dimethoxyphenyl)-1-oxopropan-2-yl 3-(3,4-bis(tert-butyldimethylsilyloxy)phenyl)acrylate

There total 6 articles about (E)-1-(allyloxy)-3-(3,4-dimethoxyphenyl)-1-oxopropan-2-yl 3-(3,4-bis(tert-butyldimethylsilyloxy)phenyl)acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1322088-10-7
allyl 3-(3,4-dimethoxyphenyl)-2-hydroxypropanoate

: 203118-32-5
(E)-3-(3,4-bis((tert-butyldimethylsilyl)oxy)phenyl)acrylic acid

: 1430417-23-4
(E)-1-(allyloxy)-3-(3,4-dimethoxyphenyl)-1-oxopropan-2-yl 3-(3,4-bis(tert-butyldimethylsilyloxy)phenyl)acrylate

Guidance literature:: With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃; for 24h;
DOI:10.1016/j.ejmech.2012.09.047

Reference yield:

: 143815-52-5
(Z)-3-(3,4-dimethoxyphenyl)-2-hydroxyacrylic acid

: 1430417-23-4
(E)-1-(allyloxy)-3-(3,4-dimethoxyphenyl)-1-oxopropan-2-yl 3-(3,4-bis(tert-butyldimethylsilyloxy)phenyl)acrylate

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydroxide; sodium tetrahydroborate / methanol / 0 - 20 °C / pH 10

2: toluene-4-sulfonic acid / toluene / 10 h / 100 °C

3: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; dmap / dichloromethane / 24 h / 20 °C

With dmap; sodium tetrahydroborate; toluene-4-sulfonic acid; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; sodium hydroxide; In methanol; dichloromethane; toluene;
DOI:10.1016/j.ejmech.2012.09.047

Reference yield:

: 32255-79-1
2-hydroxy-3-(3,4-dimethoxyphenyl)propanoic acid

: 1430417-23-4
(E)-1-(allyloxy)-3-(3,4-dimethoxyphenyl)-1-oxopropan-2-yl 3-(3,4-bis(tert-butyldimethylsilyloxy)phenyl)acrylate

Guidance literature:: Multi-step reaction with 2 steps

1: toluene-4-sulfonic acid / toluene / 10 h / 100 °C

2: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; dmap / dichloromethane / 24 h / 20 °C

With dmap; toluene-4-sulfonic acid; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; toluene;
DOI:10.1016/j.ejmech.2012.09.047