CpFe(CO)2(κS-SCS2Ph)

Base Information

• Chemical Name: CpFe(CO)2(κS-SCS2Ph)
• CAS No.: 12110-89-3
• Molecular Formula: C₁₄H₁₀FeO₂S₃
• Molecular Weight: 362.277
• Mol file: 12110-89-3.mol

Synonyms:CpFe(CO)2(κS-SCS2Ph)

Chemical Property of CpFe(CO)2(κS-SCS2Ph)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of CpFe(CO)2(κS-SCS2Ph)

There total 1 articles about CpFe(CO)2(κS-SCS2Ph) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

phenyl chlorodithioformate (16911-89-0) + bis(cyclopentadienyliron dicarbonyl) disulfane (80711-20-2) → CpFe(CO)2(κS-SCS2Ph) (12110-89-3)

Guidance literature:

In diethyl ether; byproducts: C5H5Fe(CO)2Cl; (Ar); 1.2 equiv. of Et2O soln. of organic ligand added dropwise to Fe-compound in Et2O; stirred for 2 h under protection of light; stripped to dryness; redissolved in CH2Cl2; introduced to silica gel column made up in hexane; eluted with hexane; eluted with Et2O:hexane 1:1 ratio; recrystallized from CH2Cl2/hexane; elem. anal.;

DOI:10.1016/j.poly.2007.04.010

Reference yield: 62.0%

CpFe(CO)2(κS-SCS2Ph) (12110-89-3) + triphenylantimony (603-36-1) → CpFe(CO)(SbPh3)SCS2C6H5

Guidance literature:

In tetrahydrofuran; at 0 ℃; UV-irradiation; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.poly.2017.05.016

Reference yield: 58.0%

CpFe(CO)2(κS-SCS2Ph) (12110-89-3) + triphenyl-arsane (603-32-7) → CpFe(CO)(AsPh3)SCS2C6H5

Guidance literature:

In tetrahydrofuran; at 0 ℃; UV-irradiation; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.poly.2017.05.016

upstream raw materials:

phenyl chlorodithioformate

bis(cyclopentadienyliron dicarbonyl) disulfane