chlorotris(dicyclohexylphosphane)platinum(II) chloride

Base Information

• Chemical Name: chlorotris(dicyclohexylphosphane)platinum(II) chloride
• CAS No.: 65468-10-2
• Molecular Formula: C₃₆H₆₉ClP₃Pt*Cl
• Molecular Weight: 860.851
• Mol file: 65468-10-2.mol

Synonyms:chlorotris(dicyclohexylphosphane)platinum(II) chloride

Chemical Property of chlorotris(dicyclohexylphosphane)platinum(II) chloride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of chlorotris(dicyclohexylphosphane)platinum(II) chloride

There total 2 articles about chlorotris(dicyclohexylphosphane)platinum(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

platinum(II) chloride (10025-65-7) + dicyclohexylphosphane (829-84-5) → chlorotris(dicyclohexylphosphane)platinum(II) chloride (65468-10-2)

Guidance literature:

In toluene; soln. PHCy2 in toluene was added to PtCl2 and stirred overnight at room temp.; solvent was evapd., MeOH was added, soln. was filtered through Celite and concd., toluene was added, ppt. was filtered and washed with n-hexane;

DOI:10.1021/ic051198x

Reference yield: 71.0%

cis-dichlorobis(dicyclohexylphosphane)platinum(II) (122700-83-8) + dicyclohexylphosphane (829-84-5) → chlorotris(dicyclohexylphosphane)platinum(II) chloride (65468-10-2)

Guidance literature:

In toluene; soln. PHCy2 in toluene was added dropwise at room temp. to suspn. Pt complex in toluene and stirred for 6 h; ppt. was filtered and washed with hexane;

DOI:10.1021/ic051198x

Reference yield: 92.0%

silver tetrafluoroborate (14104-20-2) + chlorotris(dicyclohexylphosphane)platinum(II) chloride (65468-10-2) → [Pt(Cl)(dicyclohexylphosphine)3]BF4 (158477-42-0) + silver(I) chloride

Guidance literature:

In dichloromethane; AgBF4 was added at room temp. to soln. Pt complex in CH2Cl2; soln. was filtered through Celite, filtrate was evapd. in vacuo; elem. anal.;

DOI:10.1021/ic051198x

upstream raw materials:

cis-dichlorobis(dicyclohexylphosphane)platinum(II)

dicyclohexylphosphane

platinum(II) chloride

Downstream raw materials:

[Pt(Cl)(dicyclohexylphosphine)3]BF₄

trans-chlorobis(dicyclohexylphosphane)(dicyclohexylphosphinato)platinum(II)