3-<(trimethylsilyl)methyl>cyclohexanone enol silyl ether

Base Information

Chemical Name:3-<(trimethylsilyl)methyl>cyclohexanone enol silyl ether
CAS No.:101773-31-3
Molecular Formula:C₁₃H₂₈OSi₂
Molecular Weight:256.536
Hs Code.:

Synonyms:3-<(trimethylsilyl)methyl>cyclohexanone enol silyl ether

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Chemical Property of 3-<(trimethylsilyl)methyl>cyclohexanone enol silyl ether

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Technology Process of 3-<(trimethylsilyl)methyl>cyclohexanone enol silyl ether

There total 1 articles about 3-<(trimethylsilyl)methyl>cyclohexanone enol silyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 930-68-7
cyclohexenone

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

: 101773-31-3
3-<(trimethylsilyl)methyl>cyclohexanone enol silyl ether

Guidance literature:: With CuBr-SMe₂; In tetrahydrofuran; at -78 ℃; for 2h;
DOI:10.1021/jo00360a063

Reference yield:

: 51783-54-1
2,3-dibromo-5,8-dimethoxynaphthoquinone

: 101773-31-3
3-<(trimethylsilyl)methyl>cyclohexanone enol silyl ether

: C₂₂H₂₇BrO₅Si

: C₂₂H₂₇BrO₅Si

Guidance literature:: With tris(diethylamino)sulfonium difluorotrimethylsiliconate; In tetrahydrofuran; at -78 - 0 ℃; for 1h; Overall yield = 86 %; Overall yield = 110 mg; Inert atmosphere;
DOI:10.1021/ja307497h

Reference yield:

: 1211789-39-7
2-bromo-3-methoxy-5-methoxymethyloxynaphthoquinone

: 101773-31-3
3-<(trimethylsilyl)methyl>cyclohexanone enol silyl ether

: C₂₂H₂₇BrO₅Si

: C₂₂H₂₇BrO₅Si

Guidance literature:: With tris(diethylamino)sulfonium difluorotrimethylsiliconate; In dichloromethane; at -78 ℃; for 0.166667h; Overall yield = 76 %; Overall yield = 121 mg; Inert atmosphere;
DOI:10.1021/ja307497h