C₅₄H₇₂O₁₀Si

Base Information

Chemical Name:C₅₄H₇₂O₁₀Si
CAS No.:132375-91-8
Molecular Formula:C₅₄H₇₂O₁₀Si
Molecular Weight:909.245
Hs Code.:

C<sub>54</sub>H<sub>72</sub>O<sub>10</sub>Si

Synonyms:C₅₄H₇₂O₁₀Si

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Chemical Property of C₅₄H₇₂O₁₀Si

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Technology Process of C₅₄H₇₂O₁₀Si

There total 63 articles about C₅₄H₇₂O₁₀Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 3282-30-2
pivaloyl chloride

: 132375-90-7
C₄₉H₆₄O₉Si

: 132375-91-8
C₅₄H₇₂O₁₀Si

Guidance literature:: With pyridine; at 0 ℃; for 12h;

Reference yield:

: 132375-35-0
tert-Butyl-[(4S,5R)-4-(2-iodo-ethyl)-2-phenyl-[1,3]dioxan-5-yloxy]-dimethyl-silane

: 132375-91-8
C₅₄H₇₂O₁₀Si

Guidance literature:: Multi-step reaction with 25 steps

1: 90 percent / acetonitrile / 48 h / 80 °C

2: 1) n-BuLi / 1) THF, -78 deg C, 1 h, 2) HMPA, -78 deg C - 25 deg C, 18 h

3: 98 percent / tetrabutylammonium fluoride / tetrahydrofuran / 12 h / 25 °C

4: 74 percent / AgCO₄, NaHCO₃, 4 Angstroem molecular sieve, silicagel / nitromethane / 4 h / 25 °C

5: 95 percent / Ph₃SnH, AIBN / toluene / 2 h / 110 °C

6: 85 percent / DIBAH / CH₂Cl₂ / 1 h / -78 °C

7: NEt₃ / CH₂Cl₂ / 1 h / 0 °C

8: DBU / dimethylformamide / 2 h / 145 °C

9: m-chloroperbenzoic acid / tetrahydrofuran; H₂O / 1 h / 0 - 25 °C

10: NaBH₄ / methanol / 1 h / 0 °C

11: 1) NaIO₄, 2) NaBH₄ / 1) EtOH, H₂O, 25 deg C, 1 h, 2) MeOH, 0 deg C, 1 h

12: 82 percent / pyridine / 4 h / -20 - 0 °C

13: 97 percent / imidazole / dimethylformamide / 12 h / 25 °C

14: 98 percent / DIBAH / CH₂Cl₂ / 1 h / -78 °C

15: NEt₃ / CH₂Cl₂ / 1 h / 0 °C

16: NaI / acetone / 2 h / 56 °C

17: 92 percent / iodine / acetonitrile / 48 h / 60 °C

18: 1) n-BuLi, 2) HMPA / 1) THF, -78 - 0 deg C, 20 min, 2) -78 - 25 deg C, 3 h

19: tetrabutylammonium fluoride / tetrahydrofuran / 3 h / 25 °C

20: imidazole / dimethylformamide / 3 h / 0 °C

21: 87 percent / AgClO₄, NaHCO₃, silicagel, 3 Angstroem molecular sieve / nitromethane / 3 h / 25 °C

22: m-chloroperbenzoic acid, NaHCO₃ / CH₂Cl₂ / 0 °C

23: CH₂Cl₂ / 0.5 h / -78 °C

24: 90 percent / EtSH, Zn(OTf)2, NaHCO₃ / CH₂Cl₂ / 5 h / 25 °C

25: 86 percent / pyridine / 12 h / 0 °C

With pyridine; 1H-imidazole; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; sodium periodate; n-butyllithium; 2,2'-azobis(isobutyronitrile); 3 A molecular sieve; 4 A molecular sieve; triphenylstannane; tetrabutyl ammonium fluoride; iodine; silver perchlorate; silica gel; zinc trifluoromethanesulfonate; diisobutylaluminium hydride; sodium hydrogencarbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; 3-chloro-benzenecarboperoxoic acid; ethanethiol; sodium iodide; In tetrahydrofuran; methanol; nitromethane; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; acetonitrile;

Reference yield:

: 132375-34-9
2-[(4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-ethanol

: 132375-91-8
C₅₄H₇₂O₁₀Si

Guidance literature:: Multi-step reaction with 26 steps

1: 84 percent / I₂, PPh₃, imidazole / acetonitrile / 0.5 h / 25 °C

2: 90 percent / acetonitrile / 48 h / 80 °C

3: 1) n-BuLi / 1) THF, -78 deg C, 1 h, 2) HMPA, -78 deg C - 25 deg C, 18 h

4: 98 percent / tetrabutylammonium fluoride / tetrahydrofuran / 12 h / 25 °C

5: 74 percent / AgCO₄, NaHCO₃, 4 Angstroem molecular sieve, silicagel / nitromethane / 4 h / 25 °C

6: 95 percent / Ph₃SnH, AIBN / toluene / 2 h / 110 °C

7: 85 percent / DIBAH / CH₂Cl₂ / 1 h / -78 °C

8: NEt₃ / CH₂Cl₂ / 1 h / 0 °C

9: DBU / dimethylformamide / 2 h / 145 °C

10: m-chloroperbenzoic acid / tetrahydrofuran; H₂O / 1 h / 0 - 25 °C

11: NaBH₄ / methanol / 1 h / 0 °C

12: 1) NaIO₄, 2) NaBH₄ / 1) EtOH, H₂O, 25 deg C, 1 h, 2) MeOH, 0 deg C, 1 h

13: 82 percent / pyridine / 4 h / -20 - 0 °C

14: 97 percent / imidazole / dimethylformamide / 12 h / 25 °C

15: 98 percent / DIBAH / CH₂Cl₂ / 1 h / -78 °C

16: NEt₃ / CH₂Cl₂ / 1 h / 0 °C

17: NaI / acetone / 2 h / 56 °C

18: 92 percent / iodine / acetonitrile / 48 h / 60 °C

19: 1) n-BuLi, 2) HMPA / 1) THF, -78 - 0 deg C, 20 min, 2) -78 - 25 deg C, 3 h

20: tetrabutylammonium fluoride / tetrahydrofuran / 3 h / 25 °C

21: imidazole / dimethylformamide / 3 h / 0 °C

22: 87 percent / AgClO₄, NaHCO₃, silicagel, 3 Angstroem molecular sieve / nitromethane / 3 h / 25 °C

23: m-chloroperbenzoic acid, NaHCO₃ / CH₂Cl₂ / 0 °C

24: CH₂Cl₂ / 0.5 h / -78 °C

25: 90 percent / EtSH, Zn(OTf)2, NaHCO₃ / CH₂Cl₂ / 5 h / 25 °C

26: 86 percent / pyridine / 12 h / 0 °C

With pyridine; 1H-imidazole; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; sodium periodate; n-butyllithium; 2,2'-azobis(isobutyronitrile); 3 A molecular sieve; 4 A molecular sieve; triphenylstannane; tetrabutyl ammonium fluoride; iodine; silver perchlorate; silica gel; zinc trifluoromethanesulfonate; diisobutylaluminium hydride; sodium hydrogencarbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; ethanethiol; sodium iodide; In tetrahydrofuran; methanol; nitromethane; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; acetonitrile;