cis,trans-bis((2-dimethyl-aminoethyl)-diphenylphosphino)(dichloro)ruthenium(II)

Base Information

Chemical Name:cis,trans-bis((2-dimethyl-aminoethyl)-diphenylphosphino)(dichloro)ruthenium(II)
CAS No.:200880-91-7
Molecular Formula:C₃₂H₄₀Cl₂N₂P₂Ru
Molecular Weight:686.607
Hs Code.:

Synonyms:cis,trans-bis((2-dimethyl-aminoethyl)-diphenylphosphino)(dichloro)ruthenium(II)

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Chemical Property of cis,trans-bis((2-dimethyl-aminoethyl)-diphenylphosphino)(dichloro)ruthenium(II)

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Technology Process of cis,trans-bis((2-dimethyl-aminoethyl)-diphenylphosphino)(dichloro)ruthenium(II)

There total 4 articles about cis,trans-bis((2-dimethyl-aminoethyl)-diphenylphosphino)(dichloro)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 29679-67-2
N,N-dimethyl-2-diphenylphosphinoethylamine

: 200880-91-7
cis,trans-bis((2-dimethyl-aminoethyl)-diphenylphosphino)(dichloro)ruthenium(II)

Guidance literature:: In toluene; Ar-atmosphere; stirring Ru-complex with 2 equiv. of phosphine (room temp., 20 h, pptn.); filtration, washing (MePh, Et2O), drying (vac.), recrystn. on Et2O diffusion to CH2Cl2 soln.;
DOI:10.1016/S0020-1693(97)05721-6

Reference yield: 80.0%

: 14898-67-0
ruthenium(III) chloride trihydrate

: 29679-67-2
N,N-dimethyl-2-diphenylphosphinoethylamine

: 200880-91-7
cis,trans-bis((2-dimethyl-aminoethyl)-diphenylphosphino)(dichloro)ruthenium(II)

Guidance literature:: With Zn; In tetrahydrofuran; Ar-atmosphere; stirring RuCl3 with 2 equiv. of phosphine and 2.5 equiv. of Zn (65°C, 4 h); filtration, solvent removal, dissoln. in CH2Cl2, crystn. on Et2O diffusion into soln.; elem. anal.;
DOI:10.1016/S0020-1693(97)05721-6

Reference yield: 57.0%

: dichlorotetrakis(dimethylsulfoxide)ruthenium(II)

: 29679-67-2
N,N-dimethyl-2-diphenylphosphinoethylamine

: 200880-91-7
cis,trans-bis((2-dimethyl-aminoethyl)-diphenylphosphino)(dichloro)ruthenium(II)

Guidance literature:: In dichloromethane; addn. of 2 equiv. of ligand to Ru-complex soln., stirring (room temp., 5min); pptn. on Et2O addn. (after 3 h), dissoln. in CH2Cl2, pptn. on Et2O addn., drying (vac., refluxing EtOH, 24 h); elem. anal.;
DOI:10.1016/s0020-1693(97)05911-2