[(η5-4-methoxy-1-p-methoxyphenyl-6-phenylcyclohexadienyl)Mn(CO)3]

Base Information

• Chemical Name: [(η5-4-methoxy-1-p-methoxyphenyl-6-phenylcyclohexadienyl)Mn(CO)3]
• CAS No.: 1276654-58-0
• Molecular Formula: C₂₃H₁₉MnO₅
• Molecular Weight: 430.339
• Mol file: 1276654-58-0.mol

Synonyms:[(η5-4-methoxy-1-p-methoxyphenyl-6-phenylcyclohexadienyl)Mn(CO)3]

Chemical Property of [(η5-4-methoxy-1-p-methoxyphenyl-6-phenylcyclohexadienyl)Mn(CO)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of [(η5-4-methoxy-1-p-methoxyphenyl-6-phenylcyclohexadienyl)Mn(CO)3]

There total 1 articles about [(η5-4-methoxy-1-p-methoxyphenyl-6-phenylcyclohexadienyl)Mn(CO)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

(η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese (458566-05-7) + 4-methoxyphenylboronic acid (5720-07-0) → [(η5-4-methoxy-1-p-methoxyphenyl-6-phenylcyclohexadienyl)Mn(CO)3] (1276654-58-0)

Guidance literature:

With Na₂CO₃; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In methanol; water; (inert atm.); addn. of 1:9 water and methanol to mixt. of phenylboronic acid deriv., manganese compd., palladium compd. and Na2CO3, refluxing for 30 min; extn. (diethyl ether), washing with water, drying over MgSO4, evapn., chromy. (silica gel, petroleum ether), NMR, IR and MS;

DOI:10.1039/c0dt01270j

upstream raw materials:

(η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese

4-methoxyphenylboronic acid