4-Methoxy-4-phenyl-2,5-cyclohexadienone N-<2-<(tert-butyldimethylsiloxy)methyl>benzoyl>imine

Base Information

• Chemical Name: 4-Methoxy-4-phenyl-2,5-cyclohexadienone N-<2-<(tert-butyldimethylsiloxy)methyl>benzoyl>imine
• CAS No.: 151965-80-9
• Molecular Formula: C₂₇H₃₃NO₃Si
• Molecular Weight: 447.649

Synonyms:4-Methoxy-4-phenyl-2,5-cyclohexadienone N-<2-<(tert-butyldimethylsiloxy)methyl>benzoyl>imine

Chemical Property of 4-Methoxy-4-phenyl-2,5-cyclohexadienone N-<2-<(tert-butyldimethylsiloxy)methyl>benzoyl>imine

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Technology Process of 4-Methoxy-4-phenyl-2,5-cyclohexadienone N-<2-<(tert-butyldimethylsiloxy)methyl>benzoyl>imine

There total 4 articles about 4-Methoxy-4-phenyl-2,5-cyclohexadienone N-<2-<(tert-butyldimethylsiloxy)methyl>benzoyl>imine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

methanol (67-56-1) + N-<2-<(tert-Butyldimethylsiloxy)methyl>benzoyl>-4-aminobiphenyl (151965-79-6) → 4-Methoxy-4-phenyl-2,5-cyclohexadienone N-<2-<(tert-butyldimethylsiloxy)methyl>benzoyl>imine (151965-80-9)

Guidance literature:

With sodium hydrogencarbonate; In water; at 0 ℃; for 1.5h; single-cell anodic oxidation, platinum electrodes, a constant current 0.15 A, LiClO₄ as supporting electrolyte;

DOI:10.1021/jo00073a016

Reference yield:

2-benzofuran-1(3H)-one (87-41-2) → 4-Methoxy-4-phenyl-2,5-cyclohexadienone N-<2-<(tert-butyldimethylsiloxy)methyl>benzoyl>imine (151965-80-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 62 percent / n-BuLi / tetrahydrofuran / 0.5 h / 0 °C

2: 72 percent / imidazole / tetrahydrofuran / 1 h

3: 45 percent / NaHCO₃ / H₂O / 1.5 h / 0 °C / single-cell anodic oxidation, platinum electrodes, a constant current 0.15 A, LiClO₄ as supporting electrolyte

With 1H-imidazole; n-butyllithium; sodium hydrogencarbonate; In tetrahydrofuran; water;

DOI:10.1021/jo00073a016

Reference yield:

4-phenylalanine (92-67-1) → 4-Methoxy-4-phenyl-2,5-cyclohexadienone N-<2-<(tert-butyldimethylsiloxy)methyl>benzoyl>imine (151965-80-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 62 percent / n-BuLi / tetrahydrofuran / 0.5 h / 0 °C

2: 72 percent / imidazole / tetrahydrofuran / 1 h

3: 45 percent / NaHCO₃ / H₂O / 1.5 h / 0 °C / single-cell anodic oxidation, platinum electrodes, a constant current 0.15 A, LiClO₄ as supporting electrolyte

With 1H-imidazole; n-butyllithium; sodium hydrogencarbonate; In tetrahydrofuran; water;

DOI:10.1021/jo00073a016

upstream raw materials:

methanol

N-<2-<(tert-Butyldimethylsiloxy)methyl>benzoyl>-4-aminobiphenyl

2-benzofuran-1(3H)-one

4-phenylalanine

Downstream raw materials:

4-Methoxy-4-phenyl-2,5-cyclohexadienone N-acetylimine

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