4-(iodomethylene)azetidinone

Base Information

Chemical Name:4-(iodomethylene)azetidinone
CAS No.:112634-09-0
Molecular Formula:C₁₅H₁₈INO₃S
Molecular Weight:419.283
Hs Code.:

Synonyms:4-(iodomethylene)azetidinone

Suppliers and Price of 4-(iodomethylene)azetidinone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-(iodomethylene)azetidinone

Chemical Property:

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Technology Process of 4-(iodomethylene)azetidinone

There total 10 articles about 4-(iodomethylene)azetidinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 112634-08-9
[2-Methanesulfonyloxymethyl-1-(4-methoxy-phenyl)-4-oxo-azetidin-3-yl]-thioacetic acid S-ethyl ester

: 112634-09-0
4-(iodomethylene)azetidinone

Guidance literature:: With tetrapentylammonium iodide; potassium iodide; In benzene; for 20h; Heating;

Reference yield:

: 88315-63-3
(E)-4-methoxy-N-((E)-3-phenylallylidene)aniline

: 112634-09-0
4-(iodomethylene)azetidinone

Guidance literature:: Multi-step reaction with 6 steps

1: 52 percent / cyanuric chloride, triethylamine / CH₂Cl₂ / 1.) -40 deg C, 4 h, 2.) -40 to -18 deg C, overnight

2: 61 percent / trifluoroacetic acid / ethanol; H₂O / 72 h / 40 °C

3: 1.) O₃, 2.) dimethyl sulfide / 1.) CH₂Cl₂, -78 deg C, 30 min, 2.) room temp., 48 h

4: NaBH₄ / CH₂Cl₂ / 24 h

5: triethylamine / CH₂Cl₂ / 1.) -78 deg C, 1 h, 2.) -78 deg C to room temp.

6: 89 percent / tetrapentylammonium iodide, KI / benzene / 20 h / Heating

With sodium tetrahydroborate; 1,3,5-trichloro-2,4,6-triazine; dimethylsulfide; tetrapentylammonium iodide; ozone; triethylamine; trifluoroacetic acid; potassium iodide; In ethanol; dichloromethane; water; benzene;

Reference yield:

: 104-94-9
4-methoxy-aniline

: 112634-09-0
4-(iodomethylene)azetidinone

Guidance literature:: Multi-step reaction with 7 steps

2: 52 percent / cyanuric chloride, triethylamine / CH₂Cl₂ / 1.) -40 deg C, 4 h, 2.) -40 to -18 deg C, overnight

3: 61 percent / trifluoroacetic acid / ethanol; H₂O / 72 h / 40 °C

4: 1.) O₃, 2.) dimethyl sulfide / 1.) CH₂Cl₂, -78 deg C, 30 min, 2.) room temp., 48 h

5: NaBH₄ / CH₂Cl₂ / 24 h

6: triethylamine / CH₂Cl₂ / 1.) -78 deg C, 1 h, 2.) -78 deg C to room temp.

7: 89 percent / tetrapentylammonium iodide, KI / benzene / 20 h / Heating

With sodium tetrahydroborate; 1,3,5-trichloro-2,4,6-triazine; dimethylsulfide; tetrapentylammonium iodide; ozone; triethylamine; trifluoroacetic acid; potassium iodide; In ethanol; dichloromethane; water; benzene;