(4S,6R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[(Z)-(R)-1-hydroxy-5-(4-methoxy-benzyloxy)-2-methyl-pent-2-enyl]-2,2-dimethyl-[1,3]dioxan-5-one

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Chemical Name:(4S,6R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[(Z)-(R)-1-hydroxy-5-(4-methoxy-benzyloxy)-2-methyl-pent-2-enyl]-2,2-dimethyl-[1,3]dioxan-5-one
CAS No.:110597-98-3
Molecular Formula:C₂₇H₄₄O₇Si
Molecular Weight:508.728
Hs Code.:
Mol file:110597-98-3.mol

Synonyms:(4S,6R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[(Z)-(R)-1-hydroxy-5-(4-methoxy-benzyloxy)-2-methyl-pent-2-enyl]-2,2-dimethyl-[1,3]dioxan-5-one

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Chemical Property of (4S,6R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[(Z)-(R)-1-hydroxy-5-(4-methoxy-benzyloxy)-2-methyl-pent-2-enyl]-2,2-dimethyl-[1,3]dioxan-5-one Edit

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Technology Process of (4S,6R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[(Z)-(R)-1-hydroxy-5-(4-methoxy-benzyloxy)-2-methyl-pent-2-enyl]-2,2-dimethyl-[1,3]dioxan-5-one

There total 3 articles about (4S,6R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[(Z)-(R)-1-hydroxy-5-(4-methoxy-benzyloxy)-2-methyl-pent-2-enyl]-2,2-dimethyl-[1,3]dioxan-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 123-11-5
4-methoxy-benzaldehyde

: 110597-98-3
(4S,6R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[(Z)-(R)-1-hydroxy-5-(4-methoxy-benzyloxy)-2-methyl-pent-2-enyl]-2,2-dimethyl-[1,3]dioxan-5-one

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) H⁺, 2.) LiAlH₄, 3.) DMSO, (COCl)2, 4.) n-BuLi, 5.) DMSO, (COCl)2

2: 1.) LDA

With lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; hydrogen cation; dimethyl sulfoxide; lithium diisopropyl amide;
DOI:10.1021/jo00238a047

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 110597-98-3
(4S,6R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[(Z)-(R)-1-hydroxy-5-(4-methoxy-benzyloxy)-2-methyl-pent-2-enyl]-2,2-dimethyl-[1,3]dioxan-5-one

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) H⁺, 2.) NaIO₄, 3.) NaBH₄, 4.) DMAP, Et₃N, 5.) DMSO, (COCl)2

2: 1.) LDA

With dmap; sodium tetrahydroborate; sodium periodate; oxalyl dichloride; hydrogen cation; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide;
DOI:10.1021/jo00238a047