(E)-5-phenyl-1-trimethylsilyl-1-penten-3-yl 2-methoxybenzoate

Base Information

• Chemical Name: (E)-5-phenyl-1-trimethylsilyl-1-penten-3-yl 2-methoxybenzoate
• CAS No.: 1237539-30-8
• Molecular Formula: C₂₂H₂₈O₃Si
• Molecular Weight: 368.548
• Mol file: 1237539-30-8.mol

Synonyms:(E)-5-phenyl-1-trimethylsilyl-1-penten-3-yl 2-methoxybenzoate

Chemical Property of (E)-5-phenyl-1-trimethylsilyl-1-penten-3-yl 2-methoxybenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-5-phenyl-1-trimethylsilyl-1-penten-3-yl 2-methoxybenzoate

There total 1 articles about (E)-5-phenyl-1-trimethylsilyl-1-penten-3-yl 2-methoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

(E)-5-phenyl-1-(trimethylsilyl)pent-1-en-3-ol (72178-87-1,88508-42-3) + 2-Methoxybenzoyl chloride (21615-34-9) → (E)-5-phenyl-1-trimethylsilyl-1-penten-3-yl 2-methoxybenzoate (1237539-30-8)

Guidance literature:

With pyridine; dmap; In dichloromethane; at 0 - 20 ℃;

DOI:10.1021/ol101114r

Reference yield: 82.0%

(E)-5-phenyl-1-trimethylsilyl-1-penten-3-yl 2-methoxybenzoate (1237539-30-8) + 4-trifluoromethylphenylboronic acid (128796-39-4) → (E)-trimethyl[5-phenyl-1-(4-trifluoromethylphenyl)-2-penten-1-yl]silane (1237538-52-1) + C26H23F3O3

Guidance literature:

With silver hexafluoroantimonate; 1,10-Phenanthroline; palladium diacetate; p-benzoquinone; In 1,2-dichloro-ethane; at 25 - 60 ℃; regioselective reaction;

DOI:10.1021/ol101114r

Reference yield: 78.0%

(E)-5-phenyl-1-trimethylsilyl-1-penten-3-yl 2-methoxybenzoate (1237539-30-8) + 4-acetylphenylboronic acid (149104-90-5) → (E)-1-[4-(5-phenyl-1-trimethylsilyl-2-penten-1-yl)phenyl]ethanone (1237538-54-3) + C27H26O4

Guidance literature:

With silver hexafluoroantimonate; 1,10-Phenanthroline; palladium diacetate; p-benzoquinone; In 1,2-dichloro-ethane; at 25 - 60 ℃; regioselective reaction;

DOI:10.1021/ol101114r

upstream raw materials:

(E)-5-phenyl-1-(trimethylsilyl)pent-1-en-3-ol

2-Methoxybenzoyl chloride

Downstream raw materials:

(E)-trimethyl(5-phenyl-1-thiophen-3-yl-2-penten-1-yl)silane

(E)-trimethyl[1-(2-methylphenyl)-5-phenyl-2-penten-1-yl]silane

(E)-[1-(4-chlorophenyl)-5-phenyl-2-penten-1-yl]trimethylsilane

(E)-[1-(4-methoxyphenyl)-5-phenyl-2-penten-1-yl]trimethylsilane