benzyl thionitrite

Base Information

• Chemical Name: benzyl thionitrite
• CAS No.: 4862-09-3
• Molecular Formula: C₇H₇NOS
• Molecular Weight: 153.205
• Mol file: 4862-09-3.mol

Synonyms:benzyl thionitrite

Chemical Property of benzyl thionitrite

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of benzyl thionitrite

There total 5 articles about benzyl thionitrite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

phenylmethanethiol (100-53-8) → dibenzyl disulphide (150-60-7) + benzyl thionitrite (4862-09-3)

Guidance literature:

With hydrogenchloride; peroxynitrite; In acetonitrile; at 5 - 10 ℃; for 0.333333h; pH=0; Further Variations:; pH-values; Temperatures; reaction times; Product distribution;

DOI:10.1002/1099-0690(200101)2001:1<131::AID-EJOC131>3.0.CO;2-N

Reference yield:

2-nitro-2-nitrosopropane (5275-46-7) + phenylmethanethiol (100-53-8) → 2-nitropropane (79-46-9) + benzyl thionitrite (4862-09-3)

Guidance literature:

In acetonitrile; at 25 ℃; Equilibrium constant;

DOI:10.1021/jo900732b

Reference yield:

(iPr)2TpZn(nitrite-κ2O,O') (1158952-66-9) + phenylmethanethiol (100-53-8) → dibenzyl disulphide (150-60-7) + benzyl thionitrite (4862-09-3) + [(hydridotris(3,5-diisopropylpyrazolyl)borate)Zn(benzylsulfido)] (1158952-62-5) + nitrogen(II) oxide (10102-43-9)

Guidance literature:

In chloroform-d1; at 20 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3cc46102e

upstream raw materials:

phenylmethanethiol

2-nitro-2-nitrosopropane

(iPr)2TpZn(nitrite-κ2O,O')

Downstream raw materials:

dibenzyl disulphide

petivericin

S-benzyl phenyl-methanethiosulfonate

benzaldehyde