4-(3-thioxo-3H-1,2-dithiol-5-yl)phenyl 5-((tert-butyldimethylsilyl)oxy)-2-((4-(nitrooxy)butanoyl)oxy)benzoate

Base Information

Chemical Name:4-(3-thioxo-3H-1,2-dithiol-5-yl)phenyl 5-((tert-butyldimethylsilyl)oxy)-2-((4-(nitrooxy)butanoyl)oxy)benzoate
CAS No.:1423166-28-2
Molecular Formula:C₂₆H₂₉NO₈S₃Si
Molecular Weight:607.802
Hs Code.:

Synonyms:4-(3-thioxo-3H-1,2-dithiol-5-yl)phenyl 5-((tert-butyldimethylsilyl)oxy)-2-((4-(nitrooxy)butanoyl)oxy)benzoate

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Chemical Property of 4-(3-thioxo-3H-1,2-dithiol-5-yl)phenyl 5-((tert-butyldimethylsilyl)oxy)-2-((4-(nitrooxy)butanoyl)oxy)benzoate

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Technology Process of 4-(3-thioxo-3H-1,2-dithiol-5-yl)phenyl 5-((tert-butyldimethylsilyl)oxy)-2-((4-(nitrooxy)butanoyl)oxy)benzoate

There total 6 articles about 4-(3-thioxo-3H-1,2-dithiol-5-yl)phenyl 5-((tert-butyldimethylsilyl)oxy)-2-((4-(nitrooxy)butanoyl)oxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 18274-81-2
desmethyl anethole trithione

: 1423166-27-1
5-((tert-butyldimethylsilyl)oxy)-2-((4-(nitrooxy)butanoyl)oxy)benzoic acid

: 1423166-28-2
4-(3-thioxo-3H-1,2-dithiol-5-yl)phenyl 5-((tert-butyldimethylsilyl)oxy)-2-((4-(nitrooxy)butanoyl)oxy)benzoate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 20 ℃; for 6h; Inert atmosphere;

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1423166-28-2
4-(3-thioxo-3H-1,2-dithiol-5-yl)phenyl 5-((tert-butyldimethylsilyl)oxy)-2-((4-(nitrooxy)butanoyl)oxy)benzoate

Guidance literature:: Multi-step reaction with 5 steps

1: 1H-imidazole / dichloromethane / 18 h

2: dmap; dicyclohexyl-carbodiimide / dichloromethane / 20 °C

3: silver nitrate / acetonitrile / 6 h / 70 °C / Darkness

4: potassium dihydrogenphosphate; dihydrogen peroxide; sodium chlorite / water; acetonitrile / 2 h / 0 °C

5: dmap; dicyclohexyl-carbodiimide / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; dmap; sodium chlorite; potassium dihydrogenphosphate; dihydrogen peroxide; silver nitrate; dicyclohexyl-carbodiimide; In dichloromethane; water; acetonitrile;
DOI:10.1039/c3md00185g

Reference yield:

: 860613-37-2
5-((tert-butyldimethylsilyl)oxy)-2-hydroxybenzaldehyde

: 1423166-28-2
4-(3-thioxo-3H-1,2-dithiol-5-yl)phenyl 5-((tert-butyldimethylsilyl)oxy)-2-((4-(nitrooxy)butanoyl)oxy)benzoate

Guidance literature:: Multi-step reaction with 4 steps

1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 20 °C

2: silver nitrate / acetonitrile / 6 h / 70 °C / Darkness

3: potassium dihydrogenphosphate; dihydrogen peroxide; sodium chlorite / water; acetonitrile / 2 h / 0 °C

4: dmap; dicyclohexyl-carbodiimide / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

With dmap; sodium chlorite; potassium dihydrogenphosphate; dihydrogen peroxide; silver nitrate; dicyclohexyl-carbodiimide; In dichloromethane; water; acetonitrile;
DOI:10.1039/c3md00185g