4-methoxybenzyl 6,7-dideoxy-8-O-(2,2-dimethylpropanoyl)-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside

Base Information

Chemical Name:4-methoxybenzyl 6,7-dideoxy-8-O-(2,2-dimethylpropanoyl)-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside
CAS No.:406225-41-0
Molecular Formula:C₂₄H₃₆O₈
Molecular Weight:452.545
Hs Code.:

Synonyms:4-methoxybenzyl 6,7-dideoxy-8-O-(2,2-dimethylpropanoyl)-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside

Suppliers and Price of 4-methoxybenzyl 6,7-dideoxy-8-O-(2,2-dimethylpropanoyl)-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-methoxybenzyl 6,7-dideoxy-8-O-(2,2-dimethylpropanoyl)-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-methoxybenzyl 6,7-dideoxy-8-O-(2,2-dimethylpropanoyl)-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside

There total 5 articles about 4-methoxybenzyl 6,7-dideoxy-8-O-(2,2-dimethylpropanoyl)-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 3282-30-2
pivaloyl chloride

: 406225-40-9
4-methoxybenzyl 6,7-dideoxy-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside

: 406225-41-0
4-methoxybenzyl 6,7-dideoxy-8-O-(2,2-dimethylpropanoyl)-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 ℃; for 1h;

Reference yield:

: 333717-27-4
4-methoxybenzyl 6,7,8,-trideoxy-2,3-O-(1-methylethylidene)-α-D-manno-oct-7-enofuraniside

: 406225-41-0
4-methoxybenzyl 6,7-dideoxy-8-O-(2,2-dimethylpropanoyl)-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside

Guidance literature:: Multi-step reaction with 4 steps

1.1: pyridine

2.1: 9-BBN / tetrahydrofuran / 0.75 h / 20 °C

2.2: 90 percent / aq. H₂O₂; aq. NaOH / 30 h

3.1: KOH / methanol / 15 h

4.1: 92 percent / Et₃N; DMAP / CH₂Cl₂ / 1 h / 0 °C

With pyridine; dmap; potassium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; triethylamine; In tetrahydrofuran; methanol; dichloromethane;

Reference yield:

: 406225-37-4
5,6-anhydro-2,3-O-isopropylidene-1-O-(4-methoxybenzyl)-L-gulose

: 406225-41-0
4-methoxybenzyl 6,7-dideoxy-8-O-(2,2-dimethylpropanoyl)-2,3-O-(1-methylethylidene)-α-D-manno-octofuraniside

Guidance literature:: Multi-step reaction with 5 steps

1.1: 95 percent / CuI / tetrahydrofuran / 2 h / -30 - -10 °C

2.1: pyridine

3.1: 9-BBN / tetrahydrofuran / 0.75 h / 20 °C

3.2: 90 percent / aq. H₂O₂; aq. NaOH / 30 h

4.1: KOH / methanol / 15 h

5.1: 92 percent / Et₃N; DMAP / CH₂Cl₂ / 1 h / 0 °C

With pyridine; dmap; potassium hydroxide; copper(l) iodide; 9-borabicyclo[3.3.1]nonane dimer; triethylamine; In tetrahydrofuran; methanol; dichloromethane;