((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF₄

Base Information

Chemical Name:((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF₄
CAS No.:145088-72-8
Molecular Formula:BF₄*C₃₁H₂₆O₄P₂Re
Molecular Weight:797.504
Hs Code.:

((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF<sub>4</sub>

Synonyms:((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF₄

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Chemical Property of ((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF₄

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Technology Process of ((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF₄

There total 1 articles about ((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 14104-20-2
silver tetrafluoroborate

: 145088-73-9
(fac-(1,3-bis(diphenylphosphino)propane)tricarbonyl rhenium(I))bromide

: 145088-72-8
((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF₄

Guidance literature:: With CO; In dichloromethane; a slight excess of AgBF4 was added to a soln. of the Re-compd. in refluxing CH2Cl2 while a stream of CO was pased through the soln. for 16 h (all operations were made under Ar);; the soln. was cooled and filtered through a pad of celite; the filtrate was concd., a small amt. of ether added, and the ppt. dried in vac.; elem. anal.;;
DOI:10.1016/0022-328X(92)80053-Z

Reference yield: 96.0%

: 145088-72-8
((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF₄

: {(C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2Re(CO)3CHO}

Guidance literature:: With NaBH₄; In methanol; water; acetonitrile; byproducts: NaBF4, BH3; under argon, cooling a soln. of metal-complex (acetonitrile/methanol/water) to 0°C, addn. of slight excess of NaBH4 with stirring; filtn., drying (vac.), elem. anal.;
DOI:10.1016/0022-328X(94)88015-8

Reference yield: 96.0%

: [D]-sodium hydroxide

: 145088-72-8
((1,3-bis(diphenylphosphino)propane)tetracarbonyl rhenium(I))BF₄

: fac-(1,3-bis(diphenylphosphino)propane)hydroxycarbonyl(tricarbonyl) rhenium(I)*acetonitrile

Guidance literature:: With NaOH; In acetonitrile; 1 M aq. NaOD was added to a soln. of the Re-compd. in acetonitrile at 0 °C and the mixt. stirred briefly under argon;; the ppt. was filtered off, washed twice with hexane and dried in vac.; elem. anal.;;
DOI:10.1016/0022-328X(92)80053-Z